Chiral transition metal catalysts represent a powerful and economic tool for implementing
stereocenters in organic synthesis, with the metal center providing a strong chemical …

Cobalt has become increasingly attractive in homogeneous catalysis because of its unique
characteristics and outstanding catalytic performance in addition to being cheap and earth …

Our planet urgently needs sustainable solutions to alleviate the anthropogenic global
warming and climate change. Homogeneous catalysis has the potential to play a …

Owing to availability of various hydrogen sources, operational simplicity, and mild reaction
conditions, catalytic transfer hydrogenation (TH) has emerged as an appealing alternative …

In this account, we describe the design, synthesis and applications of tethered versions of
the Ru (II)/N‐tosyl‐1, 2‐diphenylethylene‐1, 2‐diamine (TsDPEN) class of catalyst that are …

Three new manganese complexes trans-[Mn (P–NH–NH–P)(CO) 2][Br],(14) P–NH–NH–
P=(S, S)-PPh2CH2CH2NH–CHPhCHPhNHCH2CH2PPh2), fac-[Mn (P′–NH–NH2)(CO) …

This review provides a brief overview of advances on ruthenium (II) N-heterocyclic carbene
complexes (NHCs) applied for hydrogenation reactions undertaken during the last five …

Based on the ever-increasing demand for enantiomerically pure compounds, the
development of efficient, atom-economical, and sustainable methods to produce chiral …

This article reviews over the past 10 years the development of bifunctional homogeneous
catalysts based on first row transition metals for asymmetric hydrogenation of various CC …

Straightforward access to enantiomerically enriched cis-3-benzyl-chromanols from (E)-3-
benzylidene-chromanones was developed through Rh-catalyzed asymmetric transfer …