The field of anion supramolecular chemistry has received more and more attention in recent
years. Anions with diverse types and geometries have been widely used for the synthesis of …

Spin transition (ST) materials, exhibiting spin state conversions by external stimuli, have
been studied for over a half-century and have been continuing research interests owing to …

Cooperativity among spin centres has long been the royal road in spin crossover (SCO)
research to impose magnetic bistability in terms of thermal hysteresis. In this work we access …

Alcohol effects in a series of iron (III) spin crossover complexes [Fe (qsal-Cl) 2] NO3· ROH
(R= Me 1, Et 2, 1-Pr 3) are explored. Despite the solvents differing from each other by only …

Crystals of [FeL2][BF4] 2· nMeCN (L= N-(2, 6-di {pyrazol-1-yl} pyrid-4-yl) acetamide; n= 1 or
2) and [FeL2][ClO4] 2· MeCN are isomorphous. When n= 1 the compounds exhibit an …

Molecular devices based on spin-crossover (SCO) compounds are important targets for
molecular electronics. In this study, six air-stable FeIII complexes have been prepared:[Fe …

Molecular materials that exhibit stimuli-responsive bistability are promising candidates for
the development of molecular switches and sensors. We herein report on the coexistence of …

A new terpyridine-based ligand with a pyridyl-1, 2, 4-triazoyl bidentate pocket “out the back”
has been used to synthesize monometallic CoII, FeII, and RuII complexes where the …

Four iron (III) complexes,[Fe (qsal-4-F) 2] Y· sol (Hqsal-4-F= 4-fluoro-N-(8-quinolyl)
salicylaldimine; Y= NO3–, sol= 0.91 MeOH· 0.57 H2O (1NO3); Y= PF6–(2PF6); Y= BF4 …

During last decades, significant advances have been made in iron-based spin crossover
(SCO) complexes, with a particular emphasis on achieving reversible and reproducible …