Since the prediction of the existence of metallabenzenes in 1979, metallaaromatic chemistry
has developed rapidly, due to its importance in both experimental and theoretical fields …

While the implication of the aromaticity concept has been dramatically expanded to date
since its emergence in 1865, the classical [4n+ 2]/4n-electron counting protocol still plays an …

Showcases the highly beneficial features arising from the presence of main group elements
in organic materials, for the development of more sophisticated, yet simple advanced …

Metalloaromatic species are unique and important both experimentally and theoretically.
Significant progress has been made during the past few decades. New aromatic systems …

As heavier aromatic analogs of the cyclopentadienides, group 14 dianionic metalloles
exhibit more versatile reactivity and coordination modes due to the additional lone pair at the …

Herein, we present the synthesis and characterization of heteroleptic lanthanide complexes
bearing a dianionic η5-plumbole ligand in their coordination sphere. The reaction proceeds …

A new benchmark set termed SnS51 for assessing quantum chemical methods for the
computation of 119Sn NMR chemical shifts is presented. It covers 51 unique 119Sn NMR …

A family of six triple-decker complexes,{(MX) 2 [(pz) 4] 3}(Hpz= 4-nitropyrazole, MX= NaCl, 1;
NaBr, 2; NaI, 3; KCl, 4; KBr, 5, and KI, 6), exhibiting inclusion of halides into inverse 12 …

Conspectus The synthesis of dilithio-stannoles and-plumboles, dianionic aromatic
compounds containing tin and lead atoms in their π-skeletons, opened a new field of …

Research on zero-valent p-block elements is a recent hot topic in synthetic and theoretical
chemistry because of their novel electronic states having two lone pairs in both the s-and p …