Conspectus In recent years, nickel-catalyzed asymmetric coupling reactions have emerged
as efficient methods for constructing chiral C (sp3) carbon centers. Numerous novel …

Photocatalysis is a versatile and rapidly developing field with applications spanning artificial
photosynthesis, photo-biocatalysis, photoredox catalysis in solution or supramolecular …

This manuscript details the development of an asymmetric variant for the Ni-photoredox α-
arylation of tetrahydrofuran (THF), which was originally reported in a racemic fashion by …

The synthesis of axially chiral biaryls continues to garner significant attention in the scientific
community. In this work, we introduce a Ni-catalyzed desymmetrization strategy for prochiral …

Metallaphotoredox catalysis can unlock useful pathways for transforming organic reactants
into desirable products, largely due to the conversion of photon energy into chemical …

NiII 2, 2′-bipyridine complexes are commonly invoked intermediates in metallaphotoredox
cross-coupling reactions. Despite their ubiquity, design principles targeting improved …

We report a dual Ni/photoredox-catalyzed cross-coupling method for propargyl carbonates
and nonactivated alkyl bromides, facilitating the synthesis of a variety of substituted allenes …

The mechanism of visible light-driven Ni–C (aryl) bond homolysis in (2, 2′-bipyridine) NiII
(aryl)(halide) complexes, which play a crucial role in metallaphotoredox catalysis for cross …

Thomas C. Maier's group has reported a synergistic Ir/Ni catalysis method for the synthesis
of C (sp2)–C (sp3) bonds through an amino radical transfer (ART) strategy to generate alkyl …

The fundamental transitions of metal-based photocatalysts from ground to excited states are
typically metal-to-ligand or ligand-to-metal charge transfer, which require high-energy visible …