Arene-, Chlorido-, and Imido-Uranium Bis-and Tris (boryloxide) Complexes
We introduce the boryloxide ligand {(HCNDipp) 2BO}−(NBODipp, Dipp= 2, 6-di-
isopropylphenyl) to actinide chemistry. Protonolysis of [U {N (SiMe3) 2} 3] with 3 equiv of …
isopropylphenyl) to actinide chemistry. Protonolysis of [U {N (SiMe3) 2} 3] with 3 equiv of …
Instantaneous and phosphine-catalyzed arene binding and reduction by U (III) complexes
PL Arnold, CJV Halliday, L Puig-Urrea… - Inorganic …, 2021 - ACS Publications
Neutral arenes such as benzene have never been considered suitable ligands for
electropositive actinide cations, yet we find that even simple UIII UX3 aryloxide complexes …
electropositive actinide cations, yet we find that even simple UIII UX3 aryloxide complexes …
Theoretical Investigation of Catalytic Water Splitting by the Arene-Anchored Actinide Complexes
ZC Yang, HX Cai, R Bacha, SD Ding… - Inorganic Chemistry, 2022 - ACS Publications
Actinide complexes, which could enable the electrocatalytic H2O reduction, are not well
documented because of the fact that actinide-containing catalysts are precluded by …
documented because of the fact that actinide-containing catalysts are precluded by …
Electrochemical Activation and Functionalization of the Uranyl Ion
Interconversion of the oxidation states of uranium enables separations and reactivity
schemes involving this element and contributes to technologies for recycling of spent …
schemes involving this element and contributes to technologies for recycling of spent …
In silico design criteria for high blocking barrier uranium (iii) SIMs
S Dey, G Rajaraman - Chemical Communications, 2022 - pubs.rsc.org
A combination of DFT and ab initio CASSCF/PT2 calculations on U (III) fictitious models and
numerous reported X-ray structures unveils several geometries from coordination number 1 …
numerous reported X-ray structures unveils several geometries from coordination number 1 …
Rare-Earth Metal Boroxide with Formal Triple Metal–Oxygen Orbital Interaction: Synthesis from B(C6F5)3·H2O and Radical-Anion Ligated Rare-Earth Metal …
Rare-earth metal boroxides are not only rare and of great synthetic challenge but also
important theoretically due to their unrevealed bonding characteristics. In this paper, we …
important theoretically due to their unrevealed bonding characteristics. In this paper, we …
Continuous Shape Measures Study of the Coordination Spheres of Actinide Complexes–Part 1: Low Coordination Numbers
S Alvarez - European Journal of Inorganic Chemistry, 2021 - Wiley Online Library
Structural analyses of a large set of molecular structures of actinide compounds allow us to
establish trends for stereochemical preferences, common distortion paths, geometrical …
establish trends for stereochemical preferences, common distortion paths, geometrical …
Inverse coordination chemistry: oxocarbons, other polyoxo carbocyclic molecules and oxygen heterocycles as coordination centers. Topology and systematization
I Haiduc - Journal of Coordination Chemistry, 2020 - Taylor & Francis
This review presents inverse coordination complexes (ie metal compounds displaying an
arrangement of acceptor and donor sites opposite to that occurring in conventional …
arrangement of acceptor and donor sites opposite to that occurring in conventional …
Inverse coordination complexes. Carbon monoxide, carbon dioxide, carbonate, acyclic polyolato anions, neutral polyols and polyethers as centroligands. Topologies …
I Haiduc - Journal of Coordination Chemistry, 2023 - Taylor & Francis
The article is a companion of a previous review that described topologies of inverse
coordination complexes with oxocarbons, other polyoxo carbocyclic molecules and oxygen …
coordination complexes with oxocarbons, other polyoxo carbocyclic molecules and oxygen …