Activation of dioxygen by iron and manganese complexes: a heme and nonheme perspective

S Sahu, DP Goldberg - Journal of the American Chemical Society, 2016 - ACS Publications
The rational design of well-defined, first-row transition metal complexes that can activate
dioxygen has been a challenging goal for the synthetic inorganic chemist. The activation of …

Synthetic Fe/Cu complexes: toward understanding heme-copper oxidase structure and function

SM Adam, GB Wijeratne, PJ Rogler, DE Diaz… - Chemical …, 2018 - ACS Publications
Heme-copper oxidases (HCOs) are terminal enzymes on the mitochondrial or bacterial
respiratory electron transport chain, which utilize a unique heterobinuclear active site to …

High-valent iron (IV)–oxo complexes of heme and non-heme ligands in oxygenation reactions

W Nam - Accounts of chemical research, 2007 - ACS Publications
High-valent iron (IV)–oxo species have been implicated as the key reactive intermediates in
the catalytic cycles of dioxygen activation by heme and non-heme iron enzymes. Our …

Synthetic heme-dioxygen complexes

M Momenteau, CA Reed - Chemical reviews, 1994 - ACS Publications
0009-2665/94/0794-0659 $14.00/0 fascination for molecular scientists. Our present un-
derstanding of how hemoglobin works has arisen from a notable interplay of studies on both …

Antimalarial activity of artemisinin (qinghaosu) and related trioxanes: mechanism (s) of action

JN Cumming, P Ploypradith, GH Posner - Advances in pharmacology, 1996 - Elsevier
Publisher Summary Malaria is one of the most deadly infectious diseases known to
mankind. The species of Plasmodium that cause malaria can develop resistance to …

Electronic structure and reactivity of high-valent oxo iron porphyrins

H Fujii - Coordination chemistry reviews, 2002 - Elsevier
High valent oxo iron porphyrins have been prepared and characterized as models for
compounds-I and compounds-II in heme enzymes. In this review, we survey studies of high …

Metals and lipid oxidation. Contemporary issues

KM Schaich - Lipids, 1992 - Springer
Lipid oxidation is now recognized to be a critically important reaction in physiological and
toxicological processes as well as in food products. This provides compelling reasons to …

Iron compounds and the mechanisms of the homogeneous catalysis of the activation of O2 and H2O2 and of the oxidation of organic substrates

AY Sychev, VG Isak - Russian Chemical Reviews, 1995 - iopscience.iop.org
Experimental data on the homogeneous catalysis by iron compounds of the activation of O 2
and H 2 O 2 and of their oxidation of organic substances, and the current ideas on this …

Preparation and reactivity of oxoiron (IV) porphyrins

JT Groves, Z Gross, MK Stern - Inorganic Chemistry, 1994 - ACS Publications
Oxoiron (IV) porphyrins were conveniently prepared by ligand metathesis of stable iron (III)
porphyrin cation radicals over moist basic alumina. The formation of oxoiron (IV) porphyrins …

Push-pull porphyrins as nonlinear optical materials

KS Suslick, CT Chen, GR Meredith… - Journal of the American …, 1992 - ACS Publications
“In CHC13. 4Neat.“In acetone. dln NMP.'The probe wave-length was 1.91 pm, derived from
H2 Raman shifting of a 10 ns pulsed Nd: YAG laser (1.06 pm), as described in ref 14. Data …