The local vibrational mode theory and its place in the vibrational spectroscopy arena
E Kraka, M Quintano, HW La Force… - The Journal of …, 2022 - ACS Publications
This Feature Article starts highlighting some recent experimental and theoretical advances
in the field of IR and Raman spectroscopy, giving a taste of the breadth and dynamics of this …
in the field of IR and Raman spectroscopy, giving a taste of the breadth and dynamics of this …
Ion and water adsorption to graphene and graphene oxide surfaces
Graphene and graphene oxide (GO) are two particularly promising nanomaterials for a
range of applications including energy storage, catalysis, and separations. Understanding …
range of applications including energy storage, catalysis, and separations. Understanding …
The bending mode of water: A powerful probe for hydrogen bond structure of aqueous systems
Insights into the microscopic structure and dynamics of the water's hydrogen-bonded
network are crucial to understand the role of water in biology, atmospheric and geochemical …
network are crucial to understand the role of water in biology, atmospheric and geochemical …
Asymmetric response of interfacial water to applied electric fields
Our understanding of the dielectric response of interfacial water, which underlies the
solvation properties and reaction rates at aqueous interfaces, relies on the linear response …
solvation properties and reaction rates at aqueous interfaces, relies on the linear response …
Water structure in the electrical double layer and the contributions to the total interfacial potential at different surface charge densities
B Rehl, E Ma, S Parshotam… - Journal of the …, 2022 - ACS Publications
The electric double layer governs the processes of all charged surfaces in aqueous
solutions; however, elucidating the structure of the water molecules is challenging for even …
solutions; however, elucidating the structure of the water molecules is challenging for even …
Dynamic surface tension of surfactants in the presence of high salt concentrations
We study the influence of high NaCl concentrations on the equilibrium and dynamic surface
tensions of ionic (CTAB) and nonionic (Tween 80) surfactant solutions. Equilibrium surface …
tensions of ionic (CTAB) and nonionic (Tween 80) surfactant solutions. Equilibrium surface …
Role of ions on the surface-bound water structure at the silica/water interface: Identifying the spectral signature of stability
Isolating the hydrogen-bonding structure of water immediately at the surface is challenging,
even with surface-specific techniques like sum-frequency generation (SFG), because of the …
even with surface-specific techniques like sum-frequency generation (SFG), because of the …
The Solvation-Induced Onsager Reaction Field Rather than the Double-Layer Field Controls CO2 Reduction on Gold
Q Zhu, SK Wallentine, GH Deng, JA Rebstock… - JACS Au, 2022 - ACS Publications
The selectivity and activity of the carbon dioxide reduction (CO2R) reaction are sensitive
functions of the electrolyte cation. By measuring the vibrational Stark shift of in situ …
functions of the electrolyte cation. By measuring the vibrational Stark shift of in situ …
Chemistry governs water organization at a graphene electrode
Knowledge of the molecular structure and orientation of interfacial water molecules next to a
potentiostatically controlled electrode surface is of fundamental and technological …
potentiostatically controlled electrode surface is of fundamental and technological …
The hydrogen-bonding dynamics of water to a nitrile-functionalized electrode is modulated by voltage according to ultrafast 2D IR spectroscopy
We report the hydrogen-bonding dynamics of water to a nitrile-functionalized and plasmonic
electrode surface as a function of applied voltage. The surface-enhanced two-dimensional …
electrode surface as a function of applied voltage. The surface-enhanced two-dimensional …