Migratory insertion of CO into a Au–C bond
A MeDalPhos-ligated gold (III) metallafluorene complex, generated via C–C oxidative
addition of biphenylene, reacts with CO to produce 9-fluorenone. Experimental and …
addition of biphenylene, reacts with CO to produce 9-fluorenone. Experimental and …
Bond-dissociation energies to probe pyridine electronic effects on organogold (III) complexes: from methodological developments to application in π-backdonation …
L Bourehil, C Soep, S Seng, S Dutrannoy… - Inorganic …, 2023 - ACS Publications
In this work, we report on the synthesis of several organogold (III) complexes based on 4,
4′-diterbutylbiphenyl (C^ C) and 2, 6-bis (4-terbutylphenyl) pyridine (C^ N^ C) ligands and …
4′-diterbutylbiphenyl (C^ C) and 2, 6-bis (4-terbutylphenyl) pyridine (C^ N^ C) ligands and …
Revisiting the Bonding Model for Gold (I) Species: The Importance of Pauli Repulsion Revealed in a Gold (I)‐Cyclobutadiene Complex
Understanding the bonding of gold (I) species has been central to the development of gold
(I) catalysis. Herein, we present the synthesis and characterization of the first gold (I) …
(I) catalysis. Herein, we present the synthesis and characterization of the first gold (I) …
Energetics of key Au (iii)-substrate adducts relevant to catalytic hydroarylation of alkynes
M Regnacq, D Lesage, MSM Holmsen, K Miqueu… - Dalton …, 2023 - pubs.rsc.org
(P, C)-cyclometalated Au (III) complexes have shown remarkable ability to catalyze the
intermolecular hydroarylation of alkynes. Evidence of an outer-sphere mechanism has been …
intermolecular hydroarylation of alkynes. Evidence of an outer-sphere mechanism has been …
Gold‐Catalyzed Alkoxy‐Carbonylation of Aryl and Vinyl Iodides
VW Bhoyare, A Bera, V Gandon… - Angewandte Chemie, 2024 - Wiley Online Library
Herein, for the first time, we disclose the gold‐catalyzed alkoxy‐carbonylation of aryl and
vinyl iodides utilizing ligand‐enabled Au (I)/Au (III) redox catalysis. The present methodology …
vinyl iodides utilizing ligand‐enabled Au (I)/Au (III) redox catalysis. The present methodology …
Gold(III) Auracycles Featuring C(sp3)‐Au‐C(sp2) Bonds: Synthesis and Mechanistic Insights into the Cycloauration Step
JA González, A Arribas, P Tian… - Angewandte …, 2024 - Wiley Online Library
The direct auration of arenes is a key step in numerous gold‐catalyzed reactions. Although
reported more than 100 years ago, understanding of its underlying mechanism has been …
reported more than 100 years ago, understanding of its underlying mechanism has been …
Tin-Free Synthesis of 2, 2′-Biphenyl Gold (III) Complexes Using Dibenzosilol
A Ahrens, LFP Karger, F Rominger, M Rudolph… - …, 2023 - ACS Publications
Gold (III) complexes with dianionic 2, 2′-biphenyl ligands stand out for their oxophilic Lewis
acid character in combination with a stable and well-defined square planar geometry. They …
acid character in combination with a stable and well-defined square planar geometry. They …
Étude des effets électroniques de ligand dans des complexes organométalliques de fer et d'or par spectrométrie de masse
L Bourehil - 2023 - theses.hal.science
La chimie organométallique est un processus clé dans la catalyse homogène et donne
accès à une large gamme de produits et de réactions. Par leurs effets stériques et …
accès à une large gamme de produits et de réactions. Par leurs effets stériques et …