Enediynes, enyne‐allenes, their reactions, and beyond
E Kraka, D Cremer - Wiley Interdisciplinary Reviews …, 2014 - Wiley Online Library
Enediynes undergo a Bergman cyclization reaction to form the labile 1, 4‐didehy‐
drobenzene (p‐benzyne) biradical. The energetics of this reaction and the related Schreiner …
drobenzene (p‐benzyne) biradical. The energetics of this reaction and the related Schreiner …
Synthesis of succinimides via intramolecular Alder-ene reaction of 1, 6-enynes
X Chen, Y Lu, Z Guan, L Gu, C Chen, H Zhu… - Organic …, 2021 - ACS Publications
A novel and convenient method has been developed for the facile synthesis of
functionalized succinimide derivatives via intramolecular Alder-ene reaction of 1, 6-enynes …
functionalized succinimide derivatives via intramolecular Alder-ene reaction of 1, 6-enynes …
Base-catalyzed Schmittel cycloisomerization of o-phenylenediyne-linked bis (arenol) s to indeno [1, 2-c] chromenes
M Furusawa, K Arita, T Imahori, K Igawa, K Tomooka… - Tetrahedron …, 2013 - Elsevier
We describe the transition metal-free base-catalyzed Schmittel cycloisomerization reactions
of o-phenylene-linked bis (arenol) s to indeno [1, 2-c] chromene derivatives through …
of o-phenylene-linked bis (arenol) s to indeno [1, 2-c] chromene derivatives through …
Copper(I)-Catalyzed Syntheses of Benzo[b]fluorenes by the Cascade Reactions of 2-Alkynylbenzaldehyde N-Tosylhydrazones and Aromatic Terminal Alkynes
J Lv, H Liu, L Lu, R Hua - The Journal of Organic Chemistry, 2022 - ACS Publications
Benzo [b] fluorenes were synthesized via CuI-catalyzed cascade reactions of 2-
alkynylbenzaldehyde N-tosylhydrazones and aromatic terminal alkynes in the presence of …
alkynylbenzaldehyde N-tosylhydrazones and aromatic terminal alkynes in the presence of …
Copper-catalyzed direct coupling of unprotected propargylic alcohols with P (O) H compounds: access to allenylphosphoryl compounds under ligand-and base-free …
G Hu, C Shan, W Chen, P Xu, Y Gao, Y Zhao - Organic letters, 2016 - ACS Publications
The first facile and efficient copper-catalyzed direct C–P cross-coupling of unprotected
propargylic alcohols with P (O) H compounds has been developed, providing a general, one …
propargylic alcohols with P (O) H compounds has been developed, providing a general, one …
Development of an Allenyne‐Alkyne [4+ 2] Cycloaddition and its Application to Total Synthesis of Selaginpulvilin A
Abstract A new [4+ 2] cycloaddition of allenyne‐alkyne is developed. The reaction is
believed to proceed with forming an α, 3‐dehydrotoluene intermediate. This species …
believed to proceed with forming an α, 3‐dehydrotoluene intermediate. This species …
Synthesis of Divergent Benzo[b]fluorenones through Cycloaromatization Reactions of 1,5-Enynols and 1,5-Diynols
B Yan, Y Fu, H Zhu, Z Chen - The Journal of Organic Chemistry, 2019 - ACS Publications
A facile and efficient synthesis of divergent benzo [b] fluorenones is described through the
use of dichlorobenzoquinone-promoted oxidative cycloaromatization reactions of acyclic 1 …
use of dichlorobenzoquinone-promoted oxidative cycloaromatization reactions of acyclic 1 …
Enynone-enabled migratory insertion and Schmittel cyclization cascade for the synthesis of furan-fused fluorenes
H Zhang, T Cao, H Luo, L Chen, S Zhu - Organic Chemistry Frontiers, 2019 - pubs.rsc.org
A new method for the synthesis of furan-/benzo-fused fluorenes through copper (I)-catalyzed
coupling of conjugated enynones or α-diazocarbonyl compounds with dialkynylbenzenes …
coupling of conjugated enynones or α-diazocarbonyl compounds with dialkynylbenzenes …
Nickel‐Catalyzed Cycloisomerization of 1, 5‐Allenynes
JC Nieto‐Carmona, I Manjón‐Mata… - Advanced Synthesis …, 2024 - Wiley Online Library
We report the Ni‐catalyzed cycloisomerization of 1, 5‐allenynes. Substrates containing
terminal alkynes afford cyclopentene derivatives, whereas internal alkynes lead to the …
terminal alkynes afford cyclopentene derivatives, whereas internal alkynes lead to the …
Base‐Catalyzed Cyclization of 1,6‐Diynyl Carboxylates Involving Propargyl‐Allenyl Isomerization: Efficient Synthesis of Benzo[b]fluorene and Its Analogues
N Sun, X Xie, G Wang, H Chen… - Advanced Synthesis & …, 2017 - Wiley Online Library
An efficient protocol for the synthesis of benzo [b] fluorenes via base‐catalyzed cyclization of
1, 6‐diynyl carbonates, esters or ethers has been developed. The reaction likely proceeds …
1, 6‐diynyl carbonates, esters or ethers has been developed. The reaction likely proceeds …