Vibrational spectroscopy and dynamics of water

F Perakis, L De Marco, A Shalit, F Tang… - Chemical …, 2016 - ACS Publications
We present an overview of recent static and time-resolved vibrational spectroscopic studies
of liquid water from ambient conditions to the supercooled state, as well as of crystalline and …

Vibrational spectroscopy as a probe of structure and dynamics in liquid water

HJ Bakker, JL Skinner - Chemical reviews, 2010 - ACS Publications
Water is, of course, a fascinating and important substance. For such a simple molecule, its
condensed phase properties are surprisingly complex. Here we might mention the many …

Aqueous basic solutions: hydroxide solvation, structural diffusion, and comparison to the hydrated proton

D Marx, A Chandra, ME Tuckerman - Chemical reviews, 2010 - ACS Publications
Many hydrogen-bonded liquids, molecular solids, and lowdimensional systems support
anomalous diffusion mechanisms of topological charge defects created by the addition or …

New insights into the role of water in biological function: Studying solvated biomolecules using terahertz absorption spectroscopy in conjunction with molecular …

V Conti Nibali, M Havenith - Journal of the American Chemical …, 2014 - ACS Publications
In life science, water is the ubiquitous solvent, sometimes even called the “matrix of life”.
There is increasing experimental and theoretical evidence that solvation water is not a …

Reorientation and allied dynamics in water and aqueous solutions

D Laage, G Stirnemann, F Sterpone… - Annual review of …, 2011 - annualreviews.org
The reorientation of a water molecule is important for a host of phenomena, ranging over—in
an only partial listing—the key dynamic hydrogen-bond network restructuring of water itself …

Correlating the experimentally determined CO adsorption enthalpy with the electrochemical CO reduction performance on Cu surfaces

H Xiong, Q Sun, K Chen, Y Xu… - Angewandte Chemie …, 2023 - Wiley Online Library
CO binding energy has been widely employed as a descriptor for effective catalysts in the
electrochemical CO2 and CO reduction reactions (CO (2) RR), however, it has yet to be …

Mechanisms of acceleration and retardation of water dynamics by ions

G Stirnemann, E Wernersson… - Journal of the …, 2013 - ACS Publications
There are fundamental and not yet fully resolved questions concerning the impact of solutes,
ions in particular, on the structure and dynamics of water, which can be formulated as …

Dynamics of water interacting with interfaces, molecules, and ions.

MD Fayer - Accounts of chemical research, 2012 - ACS Publications
Water is a critical component of many chemical processes, in fields as diverse as biology
and geology. Water in chemical, biological, and other systems frequently occurs in very …

Analysis of water in confined geometries and at interfaces

MD Fayer, NE Levinger - Annual review of analytical chemistry, 2010 - annualreviews.org
The properties of water depend on its extended hydrogen bond network and the continual
picosecond–time scale structural evolution of the network. Water molecules in confined …

Water dynamics and structure of highly concentrated LiCl solutions investigated using ultrafast infrared spectroscopy

SA Roget, KA Carter-Fenk… - Journal of the American …, 2022 - ACS Publications
In highly concentrated salt solutions, the water hydrogen bond (H-bond) network is
completely disrupted by the presence of ions. Water is forced to restructure as dictated by …