Acid‐catalyzed Disulfide‐mediated Reversible Polymerization for Recyclable Dynamic Covalent Materials

BS Wang, Q Zhang, ZQ Wang, CY Shi… - Angewandte Chemie …, 2023 - Wiley Online Library
Abstract Poly (1, 2‐dithiolane) s are a family of intrinsically recyclable polymers due to their
dynamic covalent disulfide linkages. Despite the common use of thiolate‐initiated anionic …

Accessing pluripotent materials through tempering of dynamic covalent polymer networks

NR Boynton, JM Dennis, ND Dolinski, CA Lindberg… - Science, 2024 - science.org
Pluripotency, which is defined as a system not fixed as to its developmental potentialities, is
typically associated with biology and stem cells. Inspired by this concept, we report synthetic …

Enhancing the Equilibrium of Dynamic Thia-Michael Reactions through Heterocyclic Design

AE Crolais, ND Dolinski, NR Boynton… - Journal of the …, 2023 - ACS Publications
Although the catalyst-free dynamic thia-Michael (tM) reaction has been leveraged for a
range of significant applications in materials science and pharmaceutical development …

Synthesis, Recycling and High‐Throughput Reprocessing of Phase‐Separated Vitrimer‐Thermoplastic Blends

LMA Joosten, P Cassagnau… - Advanced Functional …, 2024 - Wiley Online Library
Phase‐separated polymer blends including a transesterification vitrimer and polypropylene
are synthesized from widely available precursors through reactive processing. It is shown …

Universal scaling of shear thickening transitions

M Ramaswamy, I Griniasty, DB Liarte, A Shetty… - Journal of …, 2023 - pubs.aip.org
Nearly, all dense suspensions undergo dramatic and abrupt thickening transitions in their
flow behavior when sheared at high stresses. Such transitions occur when the dominant …

Dynamic-bond-induced sticky friction tailors non-Newtonian rheology

H Kim, M van der Naald, ND Dolinski, SJ Rowan… - Soft Matter, 2023 - pubs.rsc.org
Frictional network formation has become a new paradigm for understanding the non-
Newtonian shear-thickening behavior of dense suspensions. Recent studies have …

Fundamental Investigation on Osmotic Pressure and Phase Behavior of Novel pH-Responsive Draw Solute with Imine-Based Dynamic Covalent Chemistry

A Matsuoka, M Fukushima, E Kamio… - Industrial & …, 2023 - ACS Publications
For the forward osmosis process, a draw solution (DS) with a high osmotic pressure and
reusability is desirable. In this study, amine/aldehyde mixtures are proposed as novel pH …

Fullerene grafting in polymeric nanocomposite—a promising strategy

A Kausar - Polymer-Plastics Technology and Materials, 2023 - Taylor & Francis
This review emphasized structure and features of high performance covalently linked
polymer/fullerene nanocomposite. The polymer grafting on fullerene molecules may usually …

[HTML][HTML] Dynamics of equilibrium-linked colloidal networks

T Kwon, TA Wilcoxson, DJ Milliron… - The Journal of Chemical …, 2022 - pubs.aip.org
Colloids that attractively bond to only a few neighbors (eg, patchy particles) can form
equilibrium gels with distinctive dynamic properties that are stable in time. Here, we use a …

Cascade Initiation of Ring Opening Polymerization for Dynamic Covalent Poly (disulfide) s: One-Step Double Modification and Copoly (disulfide) Synthesis by Living …

A Mondal, S Kolay, S Santra, S Sk, S Sarkar… - …, 2024 - ACS Publications
The dynamicity and recyclability of a material are the chemical bases of sustainable future
smart materials. In this context, the poly (disulfide) s of 1, 2-dithiolane are a very significant …