Self-healing hydrophobic POSS-functionalized fluorinated copolymers via RAFT polymerization and dynamic Diels–Alder reaction

S Ponnupandian, P Mondal, T Becker… - Polymer …, 2021 - pubs.rsc.org
This investigation reports the preparation of a tailor-made copolymer of furfuryl methacrylate
(FMA) and trifluoroethyl methacrylate (TFEMA) via reversible addition–fragmentation chain …

ATRP of POSS monomers revisited: Toward high-molecular weight methacrylate–POSS (co) polymers

V Raus, E Cadova, L Starovoytova, M Janata - Macromolecules, 2014 - ACS Publications
For the first time, ATRP was successfully employed for homopolymerization of a commercial
methacrylate-functionalized polyhedral oligomeric silsesquioxane (POSS) monomer …

Hierarchical assembly of amphiphilic POSS-cyclodextrin molecules and azobenzene end-capped polymers

J Li, Z Zhou, L Ma, G Chen, Q Li - Macromolecules, 2014 - ACS Publications
Stimuli-responsive polymers have been widely studied because of their potential use in
nanocarriers and nanocontainers. In this study, a smart multistimuli responsive system was …

Cylindrical nanostructure of rigid-rod POSS-containing polymethacrylate from a star-branched block copolymer

R Goseki, A Hirao, M Kakimoto, T Hayakawa - ACS Macro Letters, 2013 - ACS Publications
A nanostructure consisting of rectangular polyhedral oligomeric silsesquioxane (POSS)
nanodomains packed into a hexagonal lattice was observed in POSS-containing A2B star …

Anomalous self-assembly and ion transport in nanostructured organic–inorganic solid electrolytes

GK Sethi, X Jiang, R Chakraborty, WS Loo… - ACS Macro …, 2018 - ACS Publications
Nanostructured solid electrolytes containing ion-conducting domains and rigid
nonconducting domains are obtained by block copolymer self-assembly. Here, we report on …

Cross-Linking Nanometer-Sized Reactive Spherosilicates to Synthesize Tuneable Hydrophobic POSiSil Foams Suitable for Applications as Sensors

S Smet, B Vallaey, SP Sree… - ACS Applied Nano …, 2023 - ACS Publications
Thin hydrophobic polyoligosiloxysilicone (POSiSil) films were synthesized on silicon wafer
substrates by spin coating reactive nanometer-sized spherosilicate solutions. Surface …

[HTML][HTML] 面向亚5 nm 图案化含硅嵌段共聚物的合成与自组装

陶永鑫, 陈蕾蕾, 刘一寰, 胡欣, 朱宁, 郭凯 - 高分子学报, 2023 - gfzxb.org
嵌段共聚物的合成及其应用是高分子科学领域的研究热点. 近年来, 国内外学者设计了一系列
新型含硅嵌段共聚物, 具有较高的Flory-Huggins 相互作用参数, 在自组装制备亚5 nm …

Synthesis and characterization of sustainable polyurethane based on epoxy soybean oil and modified by double-decker silsesquioxane

J Huang, P Jiang, X Li, Y Huang - Journal of materials science, 2016 - Springer
A series of environmentally friendly and sustainable polyurethanes using epoxy soybean oil
as feedstock were synthesized with the introduction of double-decker silsesquioxane …

Nitroxide‐mediated radical polymerization of methacryloisobutyl POSS and its block copolymers with poly(n‐acryloylmorpholine)

A Ullah, SM Shah, A Hassan, M Maric… - Journal of Polymer …, 2020 - Wiley Online Library
Nitroxide‐mediated radical polymerization (NMP) of the bulky methacryloisobutyl‐
polyhedral oligomeric silsesquioxane (POSS‐MA) is successfully achieved after optimizing …

Perpendicular orientation control in thin films of POSS-containing block copolymer domains with a top-coat surface treatment

T Seshimo, Y Utsumi, T Dazai, T Maehashi… - Polymer Journal, 2016 - nature.com
The directed self-assembly of block copolymers (BCPs) can extend the resolution of
traditional optical lithographic techniques. Recently, Si-containing BCPs have been shown …