Light-Emitting Self-Assembled Materials Based on d8 and d10 Transition Metal Complexes

VWW Yam, VKM Au, SYL Leung - Chemical reviews, 2015 - ACS Publications
The spontaneous self-organization of matters has always been one of the most fascinating
wonders in the world. Self-assembly refers to “the autonomous organization of components …

The potential of palladacycles: more than just precatalysts

J Dupont, CS Consorti, J Spencer - Chemical Reviews, 2005 - ACS Publications
The past half century has witnessed enormous growth in transition-metal organometallic
chemistry, both as a scientific discipline and as a subject for research and applications in …

Bimetallic reductive elimination from dinuclear Pd (III) complexes

DC Powers, D Benitez, E Tkatchouk… - Journal of the …, 2010 - ACS Publications
In 2009, we reported C− halogen reductive elimination reactions from dinuclear Pd (III)
complexes and implicated dinuclear intermediates in Pd (OAc) 2-catalyzed C− H oxidation …

Pyridine-Directed Palladium-Catalyzed Phosphonation of C(sp2)H Bonds.

C Li, T Yano, N Ishida, M Murakami - Angewandte Chemie, 2013 - search.ebscohost.com
The article presents a study which investigates the analogous phosphonation reaction of 2-
arylpyridines. It discusses a step-by-step stoichiometric reactions that define the mechanistic …

The chemistry of binuclear palladium (II) and platinum (II) complexes

VK Jain, L Jain - Coordination Chemistry Reviews, 2005 - Elsevier
The chemistry of binuclear palladium (II) and platinum (II) complexes has been reviewed.
This review deals with complexes derived from various classes of ligands and covers …

When applying the mercury poisoning test to palladacycle-catalyzed reactions, one should not consider the common misconception of mercury (0) selectivity

ON Gorunova, IM Novitskiy, YK Grishin… - …, 2018 - ACS Publications
The aim of this study was to demonstrate the absolute necessity of control experiments for a
correct interpretation of mercury drop test results when applied to mechanistic studies of …

To Bend or Not To Bend:  Dilemma of the Edge-Sharing Binuclear Square Planar Complexes of d8 Transition Metal Ions

G Aullón, G Ujaque, A Lledós, S Alvarez… - Inorganic …, 1998 - ACS Publications
The binuclear complexes of d8 transition metal ions of type [L2M (μ-XR n) 2ML2](n= 0 to 2)
show a wide variety of bending angles between the coordination planes of the two metal …

New palladium (II) and platinum (II) 5, 5-diethylbarbiturate complexes with 2-phenylpyridine, 2, 2′-bipyridine and 2, 2′-dipyridylamine: synthesis, structures, DNA …

C Icsel, VT Yilmaz, Y Kaya, H Samli… - Dalton …, 2015 - pubs.rsc.org
Novel palladium (II) and platinum (II) complexes of 5, 5-diethylbarbiturate (barb) with 2-
phenylpyridine (Hppy), 2, 2′-bipyridine (bpy) and 2, 2′-dipyridylamine (dpya) have been …

Electrophilic substitution reactions at the phenyl ring of the chelated 2-(2 '-Pyridyl) phenyl ligand bound to Ruthenium (II) or Osmium (II)

AM Clark, CEF Rickard, WR Roper, LJ Wright - Organometallics, 1999 - ACS Publications
Reaction between (PyPh) 2Hg (PyPh= 2-(2 '-pyridyl) phenyl) and MHCl (CO)(PPh3) 3
proceeds smoothly to form M (η2-PyPh) Cl (CO)(PPh3) 2 (M= Ru (1a); M= Os (1b)). In both …

Phosphorylation of C–H bonds of aromatic compounds using metals and metal complexes

YH Budnikova, OG Sinyashin - Russian Chemical Reviews, 2015 - iopscience.iop.org
Key achievements and current trends in the development of methods for phosphorylation of
aromatic C–H bonds catalyzed by metal salts and complexes are considered. The most …