Magnetic anisotropy in two-to eight-coordinated transition–metal complexes: Recent developments in molecular magnetism

AK Bar, C Pichon, JP Sutter - Coordination Chemistry Reviews, 2016 - Elsevier
This review considers the most recent experimental developments in the magnetic
anisotropy of mono-nuclear transition metal complexes in various coordination …

Recent progress on cyano-bridged transition-metal-based single-molecule magnets and single-chain magnets

JH Wang, ZY Li, M Yamashita, XH Bu - Coordination Chemistry Reviews, 2021 - Elsevier
Novel functional molecular-based magnetic materials, especially some members of the
Prussian blue family, have gained significant attention over the past few decades as they …

[HTML][HTML] Single-molecule magnet engineering: building-block approaches

KS Pedersen, J Bendix, R Clérac - Chemical communications, 2014 - pubs.rsc.org
Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …

Single-chain magnets: beyond the Glauber model

WX Zhang, R Ishikawa, B Breedlove, M Yamashita - RSC advances, 2013 - pubs.rsc.org
Single-chain magnets (SCMs) are one-dimensional (1D) slow-relaxing magnetic chains with
interesting fundamental properties and applications, such as information storage. The …

A toolbox of building blocks, linkers and crystallisation methods used to generate single-chain magnets

S Dhers, HLC Feltham, S Brooker - Coordination Chemistry Reviews, 2015 - Elsevier
Single-molecule magnets (SMMs) and single-chain magnets (SCMs) are potential
candidates for more dense data storage and quantum computing as well as providing …

Rhombus-Shaped Tetranuclear [Ln4] Complexes [Ln = Dy(III) and Ho(III)]: Synthesis, Structure, and SMM Behavior

V Chandrasekhar, S Hossain, S Das, S Biswas… - Inorganic …, 2013 - ACS Publications
The reaction of a new hexadentate Schiff base hydrazide ligand (LH3) with rare earth (III)
chloride salts in the presence of triethylamine as the base afforded two planar tetranuclear …

Cyano-bridged Fe (II)–Cr (III) single-chain magnet based on pentagonal bipyramid units: On the added value of aligned axial anisotropy

C Pichon, N Suaud, C Duhayon… - Journal of the …, 2018 - ACS Publications
A cyano-bridged Fe (II)–Cr (III) single-chain magnet designed to ensure a parallel
orientation of the axial anisotropy of the building units is reported. This ferromagnetic chain …

Spin-state switches in molecular materials chemistry

S Hayami, SM Holmes, MA Halcrow - Journal of Materials Chemistry C, 2015 - pubs.rsc.org
Spin-transition compounds are one of the most versatile types of molecular switch. 1–3 They
undergo an electronic rearrangement under a physical stimulus from a high-spin state, with …

Enhanced Single‐Chain Magnet Behavior via Anisotropic Exchange in a Cyano‐Bridged MoIII–MnII Chain

L Shi, D Shao, XQ Wei, KR Dunbar… - Angewandte Chemie …, 2020 - Wiley Online Library
Anisotropic magnetic exchange is of great value for the design of high performance
molecular nanomagnets. In the present work, enhanced single‐chain magnet (SCM) …

Oxamato-based coordination polymers: recent advances in multifunctional magnetic materials

T Grancha, J Ferrando-Soria, M Castellano… - Chemical …, 2014 - pubs.rsc.org
The design and synthesis of novel examples of multifunctional magnetic materials based on
the so-called coordination polymers (CPs) have become very attractive for chemists and …