[HTML][HTML] Dye-sensitized solar cells strike back

AB Muñoz-García, I Benesperi, G Boschloo… - Chemical Society …, 2021 - pubs.rsc.org
Dye-sensitized solar cells (DSCs) are celebrating their 30th birthday and they are attracting
a wealth of research efforts aimed at unleashing their full potential. In recent years, DSCs …

Theoretical modeling of electrochemical proton-coupled electron transfer

RE Warburton, AV Soudackov… - Chemical …, 2022 - ACS Publications
Proton-coupled electron transfer (PCET) plays an essential role in a wide range of
electrocatalytic processes. A vast array of theoretical and computational methods have been …

Regulating the electrochemical reduction kinetics by the steric hindrance effect for a robust Zn metal anode

S Yang, A Chen, Z Tang, Z Wu, P Li, Y Wang… - Energy & …, 2024 - pubs.rsc.org
The parasitic side reactions and dendrite growth of the Zn metal anode are two primary
issues restricting the practical application of Zn-ion batteries (ZIBs). The contradiction …

Anode chemistry in calcium ion batteries: a review

X Deng, L Li, G Zhang, X Zhao, J Hao, C Han… - Energy Storage …, 2022 - Elsevier
Large-scale energy storage and scientific research rapidly promote the research and
exploration of calcium ion batteries (CIBs) due to the abundant reservation of calcium and …

Electric double layer effects in electrocatalysis: Insights from ab initio simulation and hierarchical continuum modeling

P Li, Y Jiao, J Huang, S Chen - JACS Au, 2023 - ACS Publications
Structures of the electric double layer (EDL) at electrocatalytic interfaces, which are
modulated by the material properties, the electrolyte characteristics (eg, the pH, the types …

Direct evidence for a sequential electron transfer–proton transfer mechanism in the PCET reduction of a metal hydroxide catalyst

MC Kessinger, J Xu, K Cui, Q Loague… - Journal of the …, 2024 - ACS Publications
The proton-coupled electron transfer (PCET) mechanism for the reaction Mox–OH+ e–+
H+→ Mred–OH2 was determined through the kinetic resolution of the independent electron …

Cation-dependent interfacial structures and kinetics for outer-sphere electron-transfer reactions

B Huang, KH Myint, Y Wang, Y Zhang… - The Journal of …, 2021 - ACS Publications
The kinetics of aqueous outer-sphere electron-transfer (ET) reactions are determined in
large part by noncovalent electrostatic interactions that originate from the surrounding …

pH effects in a model electrocatalytic reaction disentangled

X Zhu, J Huang, M Eikerling - JACS Au, 2023 - ACS Publications
Varying the solution pH not only changes the reactant concentrations in bulk solution but
also the local reaction environment (LRE) that is shaped furthermore by macroscopic mass …

Electrochemistry at 2D and 3D nanoelectrodes: The interplay between interface kinetics and surface density of states

S Roy, S Singh, M Khan, E Chamanehpour, S Sain… - Electrochimica …, 2024 - Elsevier
Abstract Heterogenous Electron Transfer (HET) at electrode-electrolyte interfaces depends
strongly on the morphological features or geometry of the nanostructure used for modifying …

Kinetic evidence that the solvent barrier for electron transfer is absent in the electric double layer

RE Bangle, J Schneider, DT Conroy… - Journal of the …, 2020 - ACS Publications
Classical capacitance studies have revealed that the first layer of water present at an
aqueous metal–electrolyte interface has a dielectric constant less than 1/10th of that of bulk …