Structural Aspects of Spin Crossover. Example of the [FeIILn(NCS)2] Complexes

P Gütlich, HA Goodwin, P Guionneau… - Spin Crossover in …, 2004 - Springer
The interplay between the spin crossover and the structural properties of the complexes in
the solid state is still under investigation. In particular the following questions may be asked …

Pressure effect studies on spin crossover systems

P Gütlich, V Ksenofontov, AB Gaspar - Coordination chemistry reviews, 2005 - Elsevier
In the present review article we discuss the results of investigations of the influence of
hydrostatic pressure (up to 1.2 GPa) on the spin transition behaviour in coordination …

OctaDist: a tool for calculating distortion parameters in spin crossover and coordination complexes

R Ketkaew, Y Tantirungrotechai, P Harding… - Dalton …, 2021 - pubs.rsc.org
OctaDist is an interactive and visual program for determination of structural distortion in
octahedral coordination complexes such as spin crossover complexes, single-ion magnets …

Crystallography and spin-crossover. A view of breathing materials

P Guionneau - Dalton Transactions, 2014 - pubs.rsc.org
The spin-crossover phenomenon (SCO) is a fascinating field that potentially concerns any
material containing a (d4–d7) transition metal complex finding therefore an echo in as …

Programmable spin-state switching in a mixed-valence spin-crossover iron grid

T Matsumoto, GN Newton, T Shiga, S Hayami… - Nature …, 2014 - nature.com
Photo-switchable systems, such as discrete spin-crossover complexes and bulk iron–cobalt
Prussian blue analogues, exhibit, at a given temperature, a bistability between low-and high …

A six-coordinate ytterbium complex exhibiting easy-plane anisotropy and field-induced single-ion magnet behavior

JL Liu, K Yuan, JD Leng, L Ungur… - Inorganic …, 2012 - ACS Publications
The field-induced blockage of magnetization behavior was first observed in an YbIII-based
molecule with a trigonally distorted octahedral coordination environment. Ab initio …

The spin-states and spin-transitions of mononuclear iron (II) complexes of nitrogen-donor ligands

MA Halcrow - Polyhedron, 2007 - Elsevier
A survey of mononuclear iron (II) complexes with heterocyclic N-donor ligation is presented.
A brief introduction to spin-crossover chemistry and low-temperature spin-trapping is …

Photo-induced spin-transition: the role of the iron (II) environment distortion

M Marchivie, P Guionneau, JF Létard… - … Section B: Structural …, 2005 - journals.iucr.org
The [FeLn (NCS) 2] iron (II) spin-crossover complexes cover a wide range of magnetic
behaviour. Owing to the large number of known structural and magnetic data, this series is …

[HTML][HTML] Pressure effect investigations on spin-crossover coordination compounds

AB Gaspar, G Molnár, A Rotaru, HJ Shepherd - Comptes Rendus Chimie, 2018 - Elsevier
The piezochromic properties of spin-crossover complexes have been recognized for a long
time, with increasing pressure favouring the low spin state due to its smaller volume and …

Non‐Porous Iron (II)‐Based Sensor: Crystallographic Insights into a Cycle of Colorful Guest‐Induced Topotactic Transformations

S Rodríguez‐Jiménez, HLC Feltham… - Angewandte Chemie …, 2016 - Wiley Online Library
Materials capable of sensing volatile guests at room temperature by an easily monitored set
of outputs are of great appeal for development as chemical sensors of small volatile …