The biologically relevant coordination chemistry of iron and nitric oxide: electronic structure and reactivity
Nitric oxide (NO) is an important signaling molecule that is involved in a wide range of
physiological and pathological events in biology. Metal coordination chemistry, especially …
physiological and pathological events in biology. Metal coordination chemistry, especially …
Dinitrosyl iron complexes (DNICs): from biomimetic synthesis and spectroscopic characterization toward unveiling the biological and catalytic roles of DNICs
ML Tsai, CC Tsou, WF Liaw - Accounts of chemical research, 2015 - ACS Publications
Conspectus Dinitrosyl iron complexes (DNICs) have been recognized as storage and
transport agents of nitric oxide capable of selectively modifying crucial biological targets via …
transport agents of nitric oxide capable of selectively modifying crucial biological targets via …
Distortion of the [FeNO]2 Core in Flavodiiron Nitric Oxide Reductase Models Inhibits N–N Bond Formation and Promotes Formation of Unusual Dinitrosyl Iron …
CJ White, MO Lengel, AJ Bracken… - Journal of the …, 2022 - ACS Publications
Flavodiiron nitric oxide reductases (FNORs) carry out the reduction of nitric oxide (NO) to
nitrous oxide (N2O), allowing infectious pathogens to mitigate toxic levels of NO generated …
nitrous oxide (N2O), allowing infectious pathogens to mitigate toxic levels of NO generated …
Bioinorganic Chemistry of the Natural [Fe(NO)2] Motif: Evolution of a Functional Model for NO-Related Biomedical Application and Revolutionary Development of a …
Identification of the distinctive electron paramagnetic resonance signal at g= 2.03 in the
yeast cells and liver of mice treated with carcinogens opened the discovery and …
yeast cells and liver of mice treated with carcinogens opened the discovery and …
Uncoupled redox-inactive Lewis acids in the secondary coordination sphere entice ligand-based nitrite reduction
KT Burns, WR Marks, PM Cheung, T Seda… - Inorganic …, 2018 - ACS Publications
Metal complexes composed of redox-active pyridinediimine (PDI) ligands are capable of
forming ligand-centered radicals. In this Forum article, we demonstrate that integration of …
forming ligand-centered radicals. In this Forum article, we demonstrate that integration of …
Recent advances in multinuclear metal nitrosyl complexes
L Li, L Li - Coordination chemistry reviews, 2016 - Elsevier
The coordination chemistry of metal nitrosyls has expanded rapidly in the past decades due
to major advances of nitric oxide and its metal compounds in biology. This review article …
to major advances of nitric oxide and its metal compounds in biology. This review article …
Ligand-based reduction of nitrate to nitric oxide utilizing a proton-responsive secondary coordination sphere
M Delgado, JD Gilbertson - Chemical Communications, 2017 - pubs.rsc.org
Utilizing the proton-responsive pyridinediimine ligand [(2, 6-iPrC6H3)(NCMe)(N (iPr)
2C2H4)(NCMe) C5H3N](didpa), the ligand-based reduction of nitrate (NO3−) to nitric oxide …
2C2H4)(NCMe) C5H3N](didpa), the ligand-based reduction of nitrate (NO3−) to nitric oxide …
Insight into the Electronic Structure of Biomimetic Dinitrosyliron Complexes (DNICs): Toward the Syntheses of Amido-Bridging Dinuclear DNICs
CY Tung, YT Tseng, TT Lu, WF Liaw - Inorganic Chemistry, 2021 - ACS Publications
The ubiquitous function of nitric oxide (NO) guided the biological discovery of the natural
dinitrosyliron unit (DNIU)[Fe (NO) 2] as an intermediate/end product after Fe nitrosylation of …
dinitrosyliron unit (DNIU)[Fe (NO) 2] as an intermediate/end product after Fe nitrosylation of …
Reductive transformations of a pyrazolate-based bioinspired diiron–dinitrosyl Complex
N Kindermann, A Schober, S Demeshko… - Inorganic …, 2016 - ACS Publications
Flavo-diiron nitric oxide reductases (FNORs) are a subclass of nonheme diiron proteins in
pathogenic bacteria that reductively transform NO to N2O, thereby abrogating the nitrosative …
pathogenic bacteria that reductively transform NO to N2O, thereby abrogating the nitrosative …
Nitrite reduction by a pyridinediimine complex with a proton-responsive secondary coordination sphere
YM Kwon, M Delgado, LN Zakharov, T Seda… - Chemical …, 2016 - pubs.rsc.org
The proton-responsive pyridinediimine ligand, DEAPDI (where DEAPDI=[(2, 6-
iPrC6H3)(NCMe)(N (Et) 2C2H4)(NCMe) C5H3N]) was utilized for the reduction of NO2− to …
iPrC6H3)(NCMe)(N (Et) 2C2H4)(NCMe) C5H3N]) was utilized for the reduction of NO2− to …