Mechanical properties and peculiarities of molecular crystals

WM Awad, DW Davies, D Kitagawa… - Chemical Society …, 2023 - pubs.rsc.org
In the last century, molecular crystals functioned predominantly as a means for determining
the molecular structures via X-ray diffraction, albeit as the century came to a close the …

Design of collective motions from synthetic molecular switches, rotors, and motors

D Dattler, G Fuks, J Heiser, E Moulin, A Perrot… - Chemical …, 2019 - ACS Publications
Precise control over molecular movement is of fundamental and practical importance in
physics, biology, and chemistry. At nanoscale, the peculiar functioning principles and the …

Future‐oriented advanced diarylethene photoswitches: from molecular design to spontaneous assembly systems

HB Cheng, S Zhang, E Bai, X Cao, J Wang… - Advanced …, 2022 - Wiley Online Library
Diarylethene (DAE) photoswitch is a new and promising family of photochromic molecules
and has shown superior performance as a smart trigger in stimulus‐responsive materials …

Engineering photomechanical molecular crystals to achieve extraordinary expansion based on solid-state [2+ 2] photocycloaddition

TY Xu, F Tong, H Xu, MQ Wang, H Tian… - Journal of the American …, 2022 - ACS Publications
Photomechanical molecular crystals are promising candidates for photoactuators and can
potentially be implemented as smart materials in various fields. Here, we synthesized a new …

Mechanical bending and modulation of photoactuation properties in a one-dimensional Pb (II) coordination polymer

BB Rath, JJ Vittal - Chemistry of Materials, 2021 - ACS Publications
With emerging research on stimuli-responsive materials, dynamic crystals are at the forefront
of investigation. However, research on the mechanical properties of coordination polymers …

Organic crystal packing is key to determining the photomechanical response

CJ Cook, CJ Perry, GJO Beran - The Journal of Physical Chemistry …, 2023 - ACS Publications
Organic photomechanical crystals have great promise as molecular machines, but their
development has been hindered by a lack of clear theoretical design principles. While much …

Hybrid organic–inorganic photon-powered actuators based on aligned diarylethene nanocrystals

X Dong, F Tong, KM Hanson, RO Al-Kaysi… - Chemistry of …, 2019 - ACS Publications
When photochromic molecules are organized in a crystal, the small-scale forces generated
by molecular photoisomerization events can combine together to generate work on micro-or …

Single-Crystal-to-Single-Crystal Photosynthesis of Supramolecular Organoboron Polymers with Dynamic Effects

S Bhandary, M Belis, R Shukla, L Bourda… - Journal of the …, 2024 - ACS Publications
The solid-state synthesis of single-crystalline organic polymers, having functional properties,
remains an attractive and developing research area in polymer chemistry and materials …

Dynamic effects in crystalline coordination polymers

BB Rath, JJ Vittal - CrystEngComm, 2021 - pubs.rsc.org
This highlight presents the recent scientific developments in the mechanical properties of
crystalline coordination polymers (CPs). CPs have emerged as relatively new crystalline …

Engineering shapes and sizes of molecular crystals to achieve versatile photomechanical behaviors

F Tong, DH Qu - Langmuir, 2022 - ACS Publications
Photomechanical molecular crystals, which can directly convert light energy to mechanical
energy and do mechanical work at different scales, are promising for future photoactuators …