Progress in the catalytic reactions of CO 2 and epoxides to selectively provide cyclic or polymeric carbonates
GA Bhat, DJ Darensbourg - Green Chemistry, 2022 - pubs.rsc.org
Sustainability requires that we reuse spent carbon sources from CO2 emissions to generate
new products and materials. In this regard, carbon capture is a necessary requirement for …
new products and materials. In this regard, carbon capture is a necessary requirement for …
[HTML][HTML] Synthesis of biodegradable polymers: a review on the use of schiff-base metal complexes as catalysts for the ring opening polymerization (ROP) of cyclic …
O Santoro, X Zhang, C Redshaw - Catalysts, 2020 - mdpi.com
This review describes the recent advances (from 2008 onwards) in the use of Schiff-base
metal complexes as catalysts for the ring opening polymerization (ROP) of cyclic esters. The …
metal complexes as catalysts for the ring opening polymerization (ROP) of cyclic esters. The …
Remarkably Efficient Iridium Catalysts for Directed C(sp2)–H and C(sp3)–H Borylation of Diverse Classes of Substrates
ME Hoque, MMM Hassan… - Journal of the American …, 2021 - ACS Publications
Here we describe the discovery of a new class of C–H borylation catalysts and their use for
regioselective C–H borylation of aromatic, heteroaromatic, and aliphatic systems. The new …
regioselective C–H borylation of aromatic, heteroaromatic, and aliphatic systems. The new …
[HTML][HTML] Dynamic evolution of the active center driven by hemilabile coordination in Cu/CeO2 single-atom catalyst
Z Chen, Z Liu, X Xu - Nature Communications, 2023 - nature.com
Hemilability is an important concept in homogeneous catalysis where both the reactant
activation and the product formation can occur simultaneously through a reversible opening …
activation and the product formation can occur simultaneously through a reversible opening …
The role of dynamic metal-ligand bonds in metal-organic framework chemistry
Metal-organic frameworks (MOFs) are an emerging class of porous materials composed of
metal ions or clusters interconnected by organic ligands. Many proposed applications for …
metal ions or clusters interconnected by organic ligands. Many proposed applications for …
Mechanistic Insights into Selective Indium-Catalyzed Coupling of Epoxides and Lactones
K Hosseini, C Goonesinghe, H Roshandel… - ACS …, 2023 - ACS Publications
Spiro-orthoesters, produced from the coupling of lactones and epoxides, are presequenced
monomers capable of generating alternating poly (ether-alt-esters) after ring-opening …
monomers capable of generating alternating poly (ether-alt-esters) after ring-opening …
Cationic aluminum, gallium, and indium complexes in catalysis
HJ Jung, Y Cho, D Kim… - Catalysis Science & …, 2021 - pubs.rsc.org
Neutral heavier group 13 metals aluminum, gallium, and indium have been utilized as Lewis
acid catalysts in various organic transformations ranging from classical organic reactions to …
acid catalysts in various organic transformations ranging from classical organic reactions to …
An air stable cationic indium catalyst for formation of high-molecular-weight cyclic poly (lactic acid)
C Goonesinghe, HJ Jung, H Roshandel, C Diaz… - ACS …, 2022 - ACS Publications
Overcoming entropic constraints to selectively produce high-molecular-weight cyclic poly
(lactide)(c-PLA) is a challenge. In this work, we use an air-stable cationic alkyl indium …
(lactide)(c-PLA) is a challenge. In this work, we use an air-stable cationic alkyl indium …
Rethinking the Lewis Acidity of Cationic Gallium and Indium Catalysts
C Goonesinghe, HJ Jung, IO Betinol, JR Gaffen… - ACS …, 2023 - ACS Publications
Indium compounds are commonly considered weaker Lewis acids than their gallium
counterparts. We explore the difference in Lewis acidity of the cationic dialkylgallium [GaR2 …
counterparts. We explore the difference in Lewis acidity of the cationic dialkylgallium [GaR2 …
Synthesis of Mono-and Dinuclear Aluminum Complexes Bearing Aromatic Amino-Phenolato Ligands: A Comparative Study in the Ring-Opening Polymerization of …
Y Chen, B Li, Y Wang, X Zhu, D Yuan… - Inorganic Chemistry, 2023 - ACS Publications
Dinuclear aluminum methyl complexes bearing aromatic diamine-bridged tetra (phenolato)
ligands and the mononuclear aluminum methyl complex with the phenylamine-bridged bis …
ligands and the mononuclear aluminum methyl complex with the phenylamine-bridged bis …