Volume phase transition and related phenomena of polymer gels

M Shibayama, T Tanaka - Responsive gels: volume transitions I, 2005 - Springer
This review covers the recent advances in studies of the volume phase transition and critical
phenomena of polymer gels mostly carried out in our group from 1973 to the present. We …

Statistical topology of closed curves: Some applications in polymer physics

E Orlandini, SG Whittington - Reviews of modern physics, 2007 - APS
Topological entanglement in polymers and biopolymers is a topic that involves different
fields of science such as chemistry, biology, physics, and mathematics. One of the main …

Small angle neutron scattering study on poly (N‐isopropyl acrylamide) gels near their volume‐phase transition temperature

M Shibayama, T Tanaka, CC Han - The Journal of chemical physics, 1992 - pubs.aip.org
The small angle neutron scattering experiments were conducted on N‐isopropyl acrylamide
(NIPA) gels in D2O and on the corresponding NIPA solutions. The NIPA gels underwent a …

Network modulus and superelasticity

SP Obukhov, M Rubinstein, RH Colby - Macromolecules, 1994 - ACS Publications
We discuss the elastic modulus G and swelling/deswelling behavior of networks as a
function of their concentration< t> and their preparation state. Simple scaling ideas …

Thermal Properties of Copolymer Gels Containing N-Isopropylacrylamide

M Shibayama, S Mizutani, S Nomura - Macromolecules, 1996 - ACS Publications
The phase transition of gels containing N-isopropylacrylamide (NIPA) was investigated by
differential scanning calorimetry (DSC) and swelling measurements. The enthalpy of …

A comparison between thecoil-to-globule'transition of linear chains and the “volume phase transition” of spherical microgels

C Wu - Polymer, 1998 - Elsevier
The coil-to-globule transition of individual poly (N-isopropylacrylamide)(PNIPAM) linear
chains and the volume phase transition of spherical PNIPAM microgels were studied by a …

Smart inorganic/organic hybrid microgels: Synthesis and characterisation

M Karg, T Hellweg - Journal of Materials Chemistry, 2009 - pubs.rsc.org
Responsive hybrid colloids containing both organic and inorganic components have been
the subject of many investigations in recent years. These new materials combine the stimuli …

Universality and specificity of polymer gels viewed by scattering methods

M Shibayama - Bulletin of the Chemical Society of Japan, 2006 - academic.oup.com
Concentration fluctuations in polymer gels are composed of dynamic thermal fluctuations
and frozen inhomogeneities. Particularly, the latter is a characteristic of gels and is due to …

Biomimetic color-changing hierarchical and gradient hydrogel actuators based on salt-induced microphase separation

Y Yang, F Tian, X Wang, P Xu, W An… - ACS applied materials …, 2019 - ACS Publications
There have been more challenges for hydrogel actuators to meet the combined requirement
of discoloration, complex deformation, and simple preparation. Structural coloration is widely …

Temperature and pH-dependent swelling and copper (II) adsorption of poly (N-isopropylacrylamide) copolymer hydrogel

J Cheng, G Shan, P Pan - RSC advances, 2015 - pubs.rsc.org
Poly (N-isopropylacrylamide-co-acrylamide-co-maleic acid)(P (NIPAM-AM-MA)) hydrogel
has been synthesized by free radical polymerization. The incorporation of functional …