Synthesis of polycaprolactone: a review

M Labet, W Thielemans - Chemical society reviews, 2009 - pubs.rsc.org
Polycaprolactone (PCL) is an important polymer due to its mechanical properties, miscibility
with a large range of other polymers and biodegradability. Two main pathways to produce …

Controlled ring-opening polymerization of lactide and glycolide

O Dechy-Cabaret, B Martin-Vaca… - Chemical reviews, 2004 - ACS Publications
Synthetic petrochemical-based polymers have had a tremendous industrial impact since the
1940s. Despite the numerous advantages of these materials, two major drawbacks remain …

Stereocontrolled ring-opening polymerisation of lactide

MJ Stanford, AP Dove - Chemical Society Reviews, 2010 - pubs.rsc.org
The important advances and current trends in the stereocontrolled ring-opening
polymerisation of lactide are discussed in this tutorial review. Microstructures, structural …

Synthesis of poly (lactic acid): a review

R Mehta, V Kumar, H Bhunia… - … Science, Part C: Polymer …, 2005 - Taylor & Francis
Poly (lactic acid), a bio‐degradable polymer, has been studied extensively during the past
15 years. This paper presents a review on poly (lactic acid)(PLA) with focus on its …

Biocompatible initiators for lactide polymerization

RH Platel, LM Hodgson, CK Williams - Polymer Reviews, 2008 - Taylor & Francis
The review summarizes recent developments in the preparation and use of new initiators for
the ring opening polymerization of lactide. The review compares different classes of initiator …

Structurally well-defined group 4 metal complexes as initiators for the ring-opening polymerization of lactide monomers

A Sauer, A Kapelski, C Fliedel, S Dagorne, M Kol… - Dalton …, 2013 - pubs.rsc.org
Polylactide (PLA) is an attractive polymeric material due to its origin from annually
renewable resources and its biodegradability. The ring-opening polymerization (ROP) of …

An efficient iron catalyst for the synthesis of five‐and six‐membered organic carbonates under mild conditions

CJ Whiteoak, E Martin, MM Belmonte… - Advanced Synthesis …, 2012 - Wiley Online Library
An iron (III) amine triphenolate complex,[FeTPhOA] 2, able to efficiently catalyze the
cycloaddition of carbon dioxide to a range of terminal epoxides under mild conditions, is …

Dinuclear catalysts for the ring opening polymerization of lactide

AB Kremer, P Mehrkhodavandi - Coordination Chemistry Reviews, 2019 - Elsevier
Abstract Poly (lactic acid)(PLA) is by far the most commonly produced biodegradable
polyester. Metal-mediated ring opening polymerization of lactide is the most studied route for …

Polylactides—an overview

S Slomkowski, S Penczek… - Polymers for Advanced …, 2014 - Wiley Online Library
Aliphatic polyesters derived from lactides of various configurations (LL, DD, and DL) are
promising as materials not only for packaging and for production of many other commonly …

Group 4 complexes with aminebisphenolate ligands and their application for the ring opening polymerization of cyclic esters

AJ Chmura, MG Davidson, MD Jones, MD Lunn… - …, 2006 - ACS Publications
A series of tetradentate amine (bisphenolate) ligands have been synthesized and
complexed to Ti (IV), Zr (IV), and Hf (IV) centers. Two distinct ligand sets have been …