Uranium complexes can be stabilized in a wide range of oxidation states, ranging from UII to
UVI and a very recent example of a UI complex. This review provides a comprehensive …

The chemistry of actinide-nitrides has witnessed significant advances in the last ten years
with a large focus on uranium and a few breakthroughs with thorium. Following the early …

Uranium nitrides play important roles in dinitrogen activation and functionalization and in
chemistry for nuclear fuels, but the synthesis and isolation of the highly reactive uranium (VI) …

Dinitrogen cleavage provides an attractive but poorly studied route to the assembly of
multimetallic nitride clusters. Here, we show that the monoelectron reduction of the …

The high stability of the+ IVoxidation state limits thorium redox reactivity. Here we report the
synthesis and the redox reactivity of two Th (IV) complexes supported by the arene‐tethered …

This Perspective provides a detailed overview of the chemistry of low-valent (di-and
trivalent) uranium. The reactivity of uranium (II) and uranium (III) complexes is discussed …

The reactivity of uranium compounds towards small molecules typically occurs through
stoichiometric rather than catalytic processes. Examples of uranium catalysts reacting with …

Unsupported non-bridged uranium–carbon double bonds have long been sought after in
actinide chemistry as fundamental synthetic targets in the study of actinide-ligand multiple …

Multimetallic cooperativity is believed to play a key role in the cleavage of dinitrogen to
nitrides (N3–), but the mechanism remains ambiguous due to the lack of isolated …

Determining the electronic structure of actinide complexes is intrinsically challenging
because inter-electronic repulsion, crystal field, and spin–orbit coupling effects can be of …