Self-assembled discrete molecular architectures that show selective molecular recognition
within their internal cavities are highly desirable. Such hosts often show guest recognition …

The continued development of molecular architectures of consequence to both longstanding
and newly recognized problems demands ever evolving synthetic routes, characterizations …

In 1893, Alfred Werner described the structure of octahedral transition metal complexes and
provided the basis for assigning coordination number and oxidation state to what were then …

Since the first synthesis of cryptands and cavitands, molecular cages defined as hollow
structures enclosing a three-dimensional cavity have experienced a large development in …

The field of metallosupramolecular chemistry has advanced rapidly in recent years. Much
work in this area has focused on the formation of hollow self-assembled metal-organic …

Herein we report the first study of the oxygen reduction reaction (ORR) catalyzed by a
cofacial porphyrin scaffold accessed in high yield (overall 53%) using coordination-driven …

Recent years have seen a tremendous increase in the interest for constructing hollowed-out
molecular frameworks, for their potential uses. Metal–ligand coordination-driven self …

A rare gyrobifastigium architecture (GB) was constructed by self‐assembly of a tetradentate
donor (L) with PdII acceptor in DMSO. The GB was converted to its isomeric tetragonal barrel …

Coordination-driven self-assembly of (metallo) porphyrins can produce complex metal-
organic architectures bringing new functions and applications in, for example, molecular …

The rational design of photochemical molecular device (PMD) and its hybrid system has
great potential in improving the activity of photocatalytic hydrogen production. A series of Pd …