Electrochemical late-stage functionalization

Y Wang, S Dana, H Long, Y Xu, Y Li… - Chemical …, 2023 - ACS Publications
Late-stage functionalization (LSF) constitutes a powerful strategy for the assembly or
diversification of novel molecular entities with improved physicochemical or biological …

Electrocatalysis as an enabling technology for organic synthesis

LFT Novaes, J Liu, Y Shen, L Lu… - Chemical Society …, 2021 - pubs.rsc.org
Electrochemistry has recently gained increased attention as a versatile strategy for
achieving challenging transformations at the forefront of synthetic organic chemistry …

Advances on the merger of electrochemistry and transition metal catalysis for organic synthesis

CA Malapit, MB Prater, JR Cabrera-Pardo, M Li… - Chemical …, 2021 - ACS Publications
Synthetic organic electrosynthesis has grown in the past few decades by achieving many
valuable transformations for synthetic chemists. Although electrocatalysis has been popular …

Photons or electrons? A critical comparison of electrochemistry and photoredox catalysis for organic synthesis

NES Tay, D Lehnherr, T Rovis - Chemical reviews, 2021 - ACS Publications
Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …

Organic electrochemistry: molecular syntheses with potential

C Zhu, NWJ Ang, TH Meyer, Y Qiu… - ACS central …, 2021 - ACS Publications
Efficient and selective molecular syntheses are paramount to inter alia biomolecular
chemistry and material sciences as well as for practitioners in chemical, agrochemical, and …

Dual metalation in a two-dimensional covalent organic framework for photocatalytic C–N cross-coupling reactions

A Jati, K Dey, M Nurhuda, MA Addicoat… - Journal of the …, 2022 - ACS Publications
Covalent organic frameworks (COFs) are promising hosts in heterogeneous catalysis.
Herein, we report a dual metalation strategy in a single two-dimensional-COF TpBpy for …

Controlling Ni redox states by dynamic ligand exchange for electroreductive Csp3–Csp2 coupling

TB Hamby, MJ LaLama, CS Sevov - Science, 2022 - science.org
Cross-electrophile coupling (XEC) reactions of aryl and alkyl electrophiles are appealing but
limited to specific substrate classes. Here, we report electroreductive XEC of previously …

Recent advances in organic electrosynthesis employing transition metal complexes as electrocatalysts

C Ma, P Fang, ZR Liu, SS Xu, K Xu, X Cheng, A Lei… - Science Bulletin, 2021 - Elsevier
Organic electrosynthesis has been widely used as an environmentally conscious alternative
to conventional methods for redox reactions because it utilizes electric current as a traceless …

A Paradigm Shift in Catalysis: Electro-and Photomediated Nickel-Catalyzed Cross-Coupling Reactions

MD Palkowitz, MA Emmanuel… - Accounts of Chemical …, 2023 - ACS Publications
Conspectus Transition-metal catalyzed cross-coupling reactions are fundamental reactions
in organic chemistry, facilitating strategic bond formations for accessing natural products …

Powering the future: how can electrochemistry make a difference in organic synthesis?

TH Meyer, I Choi, C Tian, L Ackermann - Chem, 2020 - cell.com
The full control of redox events is of utmost importance to key aspects of molecular
synthesis. As a consequence, chemists have recognized the power of electrochemistry for …