Electro-organic synthesis–a 21 st century technique
D Pollok, SR Waldvogel - Chemical science, 2020 - pubs.rsc.org
The severe limitations of fossil fuels and finite resources influence the scientific community to
reconsider chemical synthesis and establish sustainable techniques. Several promising …
reconsider chemical synthesis and establish sustainable techniques. Several promising …
From protein film electrochemistry to nanoconfined enzyme cascades and the electrochemical leaf
Protein film electrochemistry (PFE) has given unrivalled insight into the properties of redox
proteins and many electron-transferring enzymes, allowing investigations of otherwise ill …
proteins and many electron-transferring enzymes, allowing investigations of otherwise ill …
The power of electrified nanoconfinement for energising, controlling and observing long enzyme cascades
G Morello, CF Megarity, FA Armstrong - Nature communications, 2021 - nature.com
Multistep enzyme-catalyzed cascade reactions are highly efficient in nature due to the
confinement and concentration of the enzymes within nanocompartments. In this way, rates …
confinement and concentration of the enzymes within nanocompartments. In this way, rates …
A nanoconfined four-enzyme cascade simultaneously driven by electrical and chemical energy, with built-in rapid, confocal recycling of NADP (H) and ATP
CF Megarity, TRI Weald, RS Heath, NJ Turner… - ACS …, 2022 - ACS Publications
The importance of energized nanoconfinement for facilitating the study and execution of
enzyme cascades that feature multiple exchangeable cofactors is demonstrated by …
enzyme cascades that feature multiple exchangeable cofactors is demonstrated by …
One-pot bioelectrocatalytic conversion of chemically inert hydrocarbons to imines
Petroleum hydrocarbons are our major energy source and an important feedstock for the
chemical industry. With the exception of combustion, the deep conversion of chemically inert …
chemical industry. With the exception of combustion, the deep conversion of chemically inert …
Exploiting bidirectional electrocatalysis by a nanoconfined enzyme cascade to drive and control enantioselective reactions
The ability to drive and observe rapid enzyme catalysis in both directions is an important and
natural consequence of immobilizing cascade components within electrode nanopores and …
natural consequence of immobilizing cascade components within electrode nanopores and …
Efficient Electrocatalytic CO2 Fixation by Nanoconfined Enzymes via a C3-to-C4 Reaction That Is Favored over H2 Production
Reduction of CO2 and its direct entry into organic chemistry is achieved efficiently and in a
highly visible way using a metal oxide electrode in which two enzyme catalysts, one for …
highly visible way using a metal oxide electrode in which two enzyme catalysts, one for …
Progress in Scaling up and Streamlining a Nanoconfined, Enzyme‐Catalyzed Electrochemical Nicotinamide Recycling System for Biocatalytic Synthesis
An electrochemically driven nicotinamide recycling system, referred to as the
'electrochemical leaf'has unique attributes that may suit it to the small‐scale industrial …
'electrochemical leaf'has unique attributes that may suit it to the small‐scale industrial …
Electrified nanoconfined biocatalysis with rapid cofactor recycling
In living cells, the overall rates of catalytic reaction chains (cascades) are massively
enhanced by nanoconfinement of enzymes in tiny enclosed volumes: presented in such a …
enhanced by nanoconfinement of enzymes in tiny enclosed volumes: presented in such a …
Exploiting electrode nanoconfinement to investigate the catalytic properties of isocitrate dehydrogenase (IDH1) and a cancer-associated variant
RA Herold, R Reinbold, CF Megarity… - The Journal of …, 2021 - ACS Publications
Human isocitrate dehydrogenase (IDH1) and its cancer-associated variant (IDH1 R132H)
are rendered electroactive through coconfinement with a rapid NADP (H) recycling enzyme …
are rendered electroactive through coconfinement with a rapid NADP (H) recycling enzyme …