Abstract The XCF 3 groups (X= O, S, Se) play an increasingly important role in modern
organic chemistry due to their unique electronegativity, lipophilic nature, metabolic stability …

This review summarizes the progress in the fluorination and fluoroalkylation of electron‐rich
systems with diverse fluorine (F) and fluoroalkyl (Rfn) reagents employing hypervalent …

A must-have resource for all the researchers working in the organofluorine and related fields
This timely two-volume set uniquely focuses on emerging fluorinated motifs beyond R-CF3 …

Conspectus Because of their unique biological, physical, and chemical properties,
organofluorine compounds play an increasingly important role in numerous areas of …

The introduction of trifluoromethylchalcogen group (CF3O, CF3S and CF3Se) has attracted
growing attention in the field of modern organofluorine chemistry. Compared with the CF3S …

Here we report a mild and general method for the trifluoromethylthiolation of aldehydes
using N-trifluoromethylthiosaccharin as the CF3S radical source and sodium decatungstate …

The use of visible light activation/photoredox chemistry for the generation of radical‐
centered chalcogen–CF3 has gained widespread interest in the last past three years. Its …

An ongoing challenge in trifluoromethylthiolation reactions is the use of less expensive and
easily available trifluoromethylthio sources. Herein, we disclose an unprecedented usage of …

A synthetic method for preparation of optically active trifluoromethylthio (SCF3) compounds
by a copper‐catalyzed regio‐and enantioselective hydroboration of 1 …

A visible‐light‐induced photocatalytic trifluoromethylthiolation/cyclization of olefinic amides
using N‐trifluoromethylthiosaccharin as the trifluoromethylthiolating reagent is described …