Main group-transition metal cluster compounds of the group 15 elements

KH Whitmire - Advances in organometallic chemistry, 1998 - books.google.com
Main group elements (E) and transition metal (M) fragments interact with one another in
interesting and often unexpected fashions. The bonding patterns that are observed may give …

Advances in the chemistry of alkyne-substituted homo-and heterometallic carbonyl clusters of the iron, cobalt and nickel triads. An update

G Gervasio, E Sappa, A Secco - Journal of Organometallic Chemistry, 2014 - Elsevier
Recent developments in the chemistry of homo-and heterometallic clusters of Iron, Cobalt
and Nickel triads substituted with alkynes and related ligands are examined. New synthetic …

Limitations of the polyhedral skeletal electron pair theory in organometallic cluster chemistry: examples in tri-and tetrametallic systems

JF Halet - Coordination chemistry reviews, 1995 - Elsevier
The Polyhedral Skeletal Electron Pair Theory (PSEP) which correlates the structural
arrangement of clusters to their electron count does much for rationalizing the structures of a …

Complexes of transition metal carbonyls with alkynes. Closo-and nido-pentagonal bipyramidal clusters

E Sappa - Journal of organometallic chemistry, 1999 - Elsevier
A short review of the synthetic methods, structures and isolobal relationships of the closo M3
(CO) 8 (RC2R′) 2 and of the nido M2 (CO) 6 (RC2R′) 2 pentagonal bipyramidal …

Coupling of Acetylide Ligands on an Electron-Rich Tetraruthenium Diphosphido Framework: Synthesis, Structure, and Reactivity Studies of Ru4 (CO) 9 (μ-PPh2) 2 …

Y Chi, AJ Carty, P Blenkiron, E Delgado… - …, 1996 - ACS Publications
Thermolysis of Ru2 (CO) 6 (μ-PPh2)(C2But)(1) in toluene afforded Ru4 (CO) 9 (μ-PPh2) 2
(C2But) 2 (2) in which the acetylide ligands are coordinated to a novel 64-electron butterfly …

1, 6-Bis (trimethylsilyl) hexa-1, 3, 5-triyne as a precursor to ruthenium clusters containing highly ethynylated ligands

PJ Low, GD Enright, AJ Carty - Journal of organometallic chemistry, 1998 - Elsevier
The reaction of 1, 6-bis (trimethylsilyl) hexa-1, 3, 5-triyne (1) with Ru3 (CO) 12 results in the
formation of the butterfly cluster Ru4 (CO) 12 (μ4-η1, η1, η2, η2-Me3SiC CC2C …

Synthesis and structure of metallocarbon clusters bearing pendant ethynyl ligands. X-ray crystal structures of Os3 (CO) 9 (μ-CO)(μ3-η1, η1, η2-Me3SiC CC2C …

PJ Low, KA Udachin, GD Enright, AJ Carty - Journal of organometallic …, 1999 - Elsevier
The reaction of 1, 6-bis (trimethylsilyl) hexa-1, 3, 5-triyne (1) with Os3 (CO) 10 (NCMe) 2
yields Os3 (CO) 9 (μ-CO)(μ3-η1, η1, η2-Me3SiC CC2C CSiMe3)(2), which on treatment …

Polycarbon Ligand Complexes:  Synthesis, Molecular Structures, and Selected EHMO Studies of Ru4, Ru5, and Ru6 Clusters with Carbon Ligands Derived from …

P Blenkiron, GD Enright, PJ Low, JF Corrigan… - …, 1998 - ACS Publications
Thermolysis of the monosubstituted cluster Ru3 (CO) 11 (Ph2PC⋮ C− C⋮ CR)(R= But, Ph,
SiMe3), obtained via CO substitution in Ru3 (CO) 12, results in P− C and Ru− Ru bond …

Phosphorus Monoxide, the Analog of NO: Generation of Coordinated PO via Hydrolysis of an Aminophosphinidene Ligand. X-ray Structure of the Anion [Ru4 (CO) 12 …

JF Corrigan, S Doherty, NJ Taylor… - Journal of the American …, 1994 - ACS Publications
Although phosphorus monoxide is a spectroscopically well defined molecule1 and a prime
candidiate for detection in interstellar space, 1 2 it remains a scientific curiosity. The lack of a …

Homogeneous hydrogenation of alkynes and of 1, 4-cyclohexadiene in the presence of the clusters Ru3 (CO) 7 (μ-PPh2) 2 (C6H4), Ru4 (CO) 11 (μ4-PPh)(C6H4) …

M Castiglioni, S Deabate, R Giordano, PJ King… - Journal of …, 1998 - Elsevier
The title complexes, containing phosphido or phosphinidene bridges, catalyze the
hydrogenation of alkynes and of 1, 4-cyclohexadiene (1, 4-CHD). The benzyne-substituted …