Electrochemistry of atomically precise metal nanoclusters
K Kwak, D Lee - Accounts of Chemical Research, 2018 - ACS Publications
Thiolate-protected metal nanoparticles containing a few to few hundred metal atoms are
interesting materials exhibiting unique physicochemical properties. They encompass the …
interesting materials exhibiting unique physicochemical properties. They encompass the …
Visible to NIR‐II Photoluminescence of Atomically Precise Gold Nanoclusters
Atomically precise gold nanoclusters (NCs) have emerged as a new class of precision
materials and attracted wide interest in recent years. One of the unique properties of such …
materials and attracted wide interest in recent years. One of the unique properties of such …
Near-unity NIR phosphorescent quantum yield from a room-temperature solvated metal nanocluster
WQ Shi, L Zeng, RL He, XS Han, ZJ Guan, M Zhou… - Science, 2024 - science.org
Metal nanoclusters have emerged as promising near-infrared (NIR)–emissive materials, but
their room-temperature photoluminescence quantum yield (PLQY), especially in solution, is …
their room-temperature photoluminescence quantum yield (PLQY), especially in solution, is …
Elucidating the Near-Infrared Photoluminescence Mechanism of Homometal and Doped M25(SR)18 Nanoclusters
More than a decade of research on the photoluminescence (PL) of classic Au25 (SR) 18 and
its doped nanoclusters (NCs) still leaves many fundamental questions unanswered due to …
its doped nanoclusters (NCs) still leaves many fundamental questions unanswered due to …
Atomically Precise Gold Nanoclusters as Model Catalysts for Identifying Active Sites for Electroreduction of CO2
Accurate identification of active sites is critical for elucidating catalytic reaction mechanisms
and developing highly efficient and selective electrocatalysts. Herein, we report the atomic …
and developing highly efficient and selective electrocatalysts. Herein, we report the atomic …
Atomically tailored gold nanoclusters for catalytic application
Recent advances in the synthetic chemistry of atomically precise metal nanoclusters (NCs)
have significantly broadened the accessible sizes and structures. Such particles are well …
have significantly broadened the accessible sizes and structures. Such particles are well …
Three-orders-of-magnitude variation of carrier lifetimes with crystal phase of gold nanoclusters
We report a three-orders-of-magnitude variation of carrier lifetimes in exotic crystalline
phases of gold nanoclusters (NCs) in addition to the well-known face-centered cubic …
phases of gold nanoclusters (NCs) in addition to the well-known face-centered cubic …
The critical number of gold atoms for a metallic state nanocluster: resolving a decades-long question
Probing the transition from a metallic state to a molecular state in gold nanoparticles is
fundamentally important for understanding the origin of surface plasmon resonance and the …
fundamentally important for understanding the origin of surface plasmon resonance and the …
Crystal phase control of gold nanomaterials by wet-chemical synthesis
Conspectus Gold (Au), a transition metal with an atomic number of 79 in the periodic table of
elements, was discovered in approximately 3000 BC Due to the ultrahigh chemical stability …
elements, was discovered in approximately 3000 BC Due to the ultrahigh chemical stability …
A mono-cuboctahedral series of gold nanoclusters: photoluminescence origin, large enhancement, wide tunability, and structure–property correlation
The origin of the near-infrared photoluminescence (PL) from thiolate-protected gold
nanoclusters (Au NCs,< 2 nm) has long been controversial, and the exact mechanism for the …
nanoclusters (Au NCs,< 2 nm) has long been controversial, and the exact mechanism for the …