Determination of nitration kinetics of p-Nitrotoluene with a homogeneously continuous microflow

J Song, Y Cui, L Sheng, Y Wang, C Du, J Deng… - Chemical Engineering …, 2022 - Elsevier
The kinetics of p-nitrotoluene nitration with mixed acid is important to industrial process
design and safety control. However, it's difficult to acquire accurate kinetic data and no …

Determination of the kinetics of chlorobenzene nitration using a homogeneously continuous microflow

Y Cui, J Song, C Du, J Deng, G Luo - AIChE Journal, 2022 - Wiley Online Library
The nitration of chlorobenzene with concentrated mixed acids is a fast and highly exothermic
process, which suffers from considerable mass transfer resistance and poor heat transfer …

Heterogeneous nitration of nitrobenzene in microreactors: Process optimization and modelling

N Jin, Y Song, J Yue, Q Wang, P Lu, Y Li… - Chemical Engineering …, 2023 - Elsevier
Aromatic nitration with mixed acid is an important step in the industrial synthesis of basic
industrial chemicals, while the highly exothermic and heterogeneous nature of the reaction …

Process hazard and thermal risk evaluation of m-xylene nitration with mixed acid

H Yao, L Ni, Y Liu, G Fu, J Jiang, Z Cheng, Y Ni… - Process Safety and …, 2023 - Elsevier
The exothermic pattern of m-xylene nitration with mixed acid in semi-batch mode was
studied by reaction calorimetry. Adiabatic temperature rise (Δ T ad) and reaction enthalpy (∆ …

Kinetic study of o-nitrotoluene nitration in a homogeneously continuous microflow

J Song, Y Cui, G Luo, J Deng, Y Wang - Reaction Chemistry & …, 2022 - pubs.rsc.org
o-Nitrotoluene nitration can produce 2, 4-dinitrotoluene and 2, 6-dinitrotoluene
simultaneously, which is also the common side-reaction of toluene mononitration. Kinetic …

Kinetics study of heterogeneous continuous-flow nitration of trifluoromethoxybenzene

Z Wen, M Yang, S Zhao, F Zhou, G Chen - Reaction Chemistry & …, 2018 - pubs.rsc.org
The kinetics and mass transfer characteristics of the nitration of trifluoromethoxybenzene
(TFMB) with a mixed acid were investigated in microchannel reactors. By assuming the …

The intensification of rapid reactions for multiphase systems in a microchannel reactor by packing microparticles

Y Su, Y Zhao, F Jiao, G Chen, Q Yuan - AIChE Journal, 2011 - Wiley Online Library
In this study, the nitration of o‐nitrotoluene (NT) with mixed acid as a model fast liquid–liquid
multiphase reaction was conducted in the packed and nonpacked microchannel reactors …

Heterogeneous toluene nitration with mixed acid in microreactors: Reaction regime, characteristics and kinetic models

R Chen, C Yao, S Zhao, X Liu, Y Lian… - Chemical Engineering …, 2024 - Elsevier
It is critical for reactor design and process safety to determine the reaction kinetics for
toluene nitration. Herein, a continuous-flow platform based on capillary microreactors was …

Nitration of nitrobenzene at high‐concentrations of sulfuric acid: Mass transfer and kinetic aspects

M Rahaman, B Mandal, P Ghosh - AIChE journal, 2010 - Wiley Online Library
This article reports studies on mass transfer and kinetics of nitration of nitrobenzene at high
concentrations of sulfuric acid in a batch reactor at different temperatures. The effects of …

Mass transfer of chlorobenzene in concentrated sulfuric acid

SVR Bandaru, P Ghosh - International Journal of Heat and Mass Transfer, 2011 - Elsevier
Mass transfer of chlorobenzene in sulfuric acid is very important in the nitration of
chlorobenzene by mixed acid. This article presents the determination of mass transfer …