The organic geochemistry of asphaltenes and occluded biomarkers

LR Snowdon, JK Volkman, Z Zhang, G Tao, P Liu - Organic Geochemistry, 2016 - Elsevier
Asphaltenes are heteroatom rich macromolecules thought to be mainly derived from the
early breaking of covalent bonds in kerogen and thus have been considered to be a lower …

Supramolecular assembly model for aggregation of petroleum asphaltenes

MR Gray, RR Tykwinski, JM Stryker, X Tan - Energy & Fuels, 2011 - ACS Publications
The components of petroleum asphaltenes exhibit complex bridged structures comprising
sulfur, nitrogen, aromatic, and naphthenic groups linked by alkyl chains. These components …

Asphaltenes: Aggregates in terms of A1 and A2 or island and archipielago structures

S Acevedo, J Castillo - ACS omega, 2023 - ACS Publications
In this work several issues related to asphaltenes and asphaltene aggregates such as
isolation of real asphaltene molecules and comparison of these with average structures …

Resins and asphaltenes of light and heavy oils: their composition and structure

TV Cheshkova, VP Sergun, EY Kovalenko… - Energy & …, 2019 - ACS Publications
The complex of physicochemical methods of analysis (elemental analysis, cryoscopy in
benzene, IR and 1H NMR spectroscopies, structural group analysis, gas chromatography …

Dissolution and suspension of asphaltenes with ionic liquids

C Zheng, M Brunner, H Li, D Zhang, R Atkin - Fuel, 2019 - Elsevier
Asphaltenes, which comprise polycyclic aromatic hydrocarbon cores with attached short
aliphatic side chains, are the most polar fraction of crude oils. Asphaltenes are prone to …

Exploring occluded compounds and their interactions with asphaltene networks using high-resolution mass spectrometry

ML Chacon-Patino, SJ Vesga-Martinez… - Energy & …, 2016 - ACS Publications
In this contribution, we use high-resolution mass spectrometry to unveil the molecular
composition of occluded compounds inside Colombian asphaltenes macrostructures. We …

Geochemical evolution of occluded hydrocarbons inside geomacromolecules: a review

B Cheng, J Zhao, C Yang, Y Tian, Z Liao - Energy & Fuels, 2017 - ACS Publications
Within geomacromolecules, such as kerogen, asphaltene, and solid bitumen, other
compounds can be adsorbed and even occluded as free molecules. The occluded …

Features of the composition of compounds trapped in asphaltenes of oils and bitumens of the Bavly oil field

YM Ganeeva, EE Barskaya, ES Okhotnikova… - Energy & …, 2021 - ACS Publications
The asphaltene aggregates are made of a well-packed and stable in benzene (toluene)
solution core and a loose-packed periphery, which can respectively occlude and adsorb the …

Environmental petroleum pollution analysis using ramped pyrolysis-gas chromatography–mass spectrometry

ME Seeley, Q Wang, H Bacosa, BE Rosenheim… - Organic …, 2018 - Elsevier
In response to the Deepwater Horizon oil spill, critical research has tracked the changes in
petroleum hydrocarbons with environmental weathering. There are limitations, however …

The hysteresis of asphaltene-trapped saturated hydrocarbons during thermal evolution

P Fang, J Wu, F Chen, Y Wang, XC Wang, K Liu… - Fuel, 2022 - Elsevier
Asphaltene-trapped (adsorbed or occluded) biomarkers are considered a valid source of
information for crude oil with severe secondary alterations. However, thermal stress might …