Catalytic oxidation processes for the upgrading of terpenes: state-of-the-art and future trends

A Denicourt-Nowicki, M Rauchdi, M Ait Ali, A Roucoux - Catalysts, 2019 - mdpi.com
Terpenic olefins constitute a relevant platform of renewable molecules, which could be used
as key intermediates for the perfumery, flavoring, and pharmaceutical industries. The …

Epoxidation of limonene and pinenes by dimethyldioxirane in microemulsions

YM Ahmat, S Kaliaguine - Catalysis Today, 2023 - Elsevier
Terpene epoxides such as limonene dioxide are known as a very important intermediates
for developing biological resins such as non-isocyanate polyurethanes. Recently, the …

The epoxidation of limonene over the TS-1 and Ti-SBA-15 catalysts

A Wróblewska - Molecules, 2014 - mdpi.com
Limonene belongs to a group of very important intermediates used in the production of fine
chemicals. This monoterpene compound can be obtained from peels of oranges or lemon …

Catalyst-free epoxidation of limonene to limonene dioxide

L Charbonneau, X Foster, D Zhao… - ACS Sustainable …, 2018 - ACS Publications
Limonene dioxide is a platform molecule for the production of new biopolymers. First
attempts at limonene epoxidation were made by using low-coordination titanium supported …

Ultrasonic and catalyst-free epoxidation of limonene and other terpenes using dimethyl dioxirane in semibatch conditions

L Charbonneau, X Foster… - … Sustainable Chemistry & …, 2018 - ACS Publications
Limonene dioxide is a key intermediate molecule for the development of biobased
polycarbonates or nonisocyanate polyurethanes. In this work the epoxidation of limonene to …

Epoxidation of limonene over low coordination Ti in Ti-SBA-16

L Charbonneau, S Kaliaguine - Applied Catalysis A: General, 2017 - Elsevier
Epoxidation of limonene was studied over Ti-SBA-16 catalysts prepared using two different
post grafting techniques. The first one consisted of an in-situ synthesis of a titanium …

Amino-modified molecular sieves for adsorptive removal of H 2 S from natural gas

J Zhang, H Song, Y Chen, T Hao, F Li, D Yuan… - RSC …, 2018 - pubs.rsc.org
Amine-modified MCM-41 adsorbents (APTMS/MCM-41, PEI/MCM-41 and AAPTS/MCM-41)
were prepared and characterized by XRD, N2 adsorption–desorption, FT-IR, TEM, SEM and …

The studies on the limonene oxidation over the microporous TS-1 catalyst

A Wróblewska, E Makuch, P Miądlicki - Catalysis Today, 2016 - Elsevier
The studies on the oxidation of limonene with 60 wt% hydrogen peroxide over the titanium
silicalite TS-1 catalyst were carried out. The influence of the following parameters was …

Controlled deposition of silica on titania-silica to alter the active site surroundings on epoxidation catalysts

MA Ardagh, DT Bregante, DW Flaherty… - ACS …, 2020 - ACS Publications
Lewis acidic Ti-SiO2 materials are workhorse oxidation catalysts, and they range from
microporous substituted zeolites to meso/macroporous materials, often with tradeoffs …

Conversion of limonene over heterogeneous catalysis: an overview

R Tomar, S Jain, P Yadav, T Bajaj… - Current Organic …, 2022 - ingentaconnect.com
The natural terpene limonene is widely found in nature. The (R)-limonene (the most
abundant enantiomer) is present in the essential oils of lemon, orange, and other citrus …