In Situ/Operando Electrocatalyst Characterization by X-ray Absorption Spectroscopy

J Timoshenko, B Roldan Cuenya - Chemical reviews, 2020 - ACS Publications
During the last decades, X-ray absorption spectroscopy (XAS) has become an
indispensable method for probing the structure and composition of heterogeneous catalysts …

On the role of metals in nitrogen‐doped carbon electrocatalysts for oxygen reduction

J Masa, W Xia, M Muhler… - Angewandte Chemie …, 2015 - Wiley Online Library
The notion of metal‐free catalysts is used to refer to carbon materials modified with
nonmetallic elements. However, some claimed metal‐free catalysts are prepared using …

Microporous Framework Induced Synthesis of Single-Atom Dispersed Fe-NC Acidic ORR Catalyst and Its in Situ Reduced Fe-N4 Active Site Identification Revealed …

M Xiao, J Zhu, L Ma, Z Jin, J Ge, X Deng, Y Hou… - Acs …, 2018 - ACS Publications
Developing highly efficient, low-cost oxygen reduction catalysts, especially in acidic
medium, is of significance toward fuel cell commercialization. Although pyrolyzed Fe-NC …

On an Easy Way To Prepare Metal–Nitrogen Doped Carbon with Exclusive Presence of MeN4-type Sites Active for the ORR

UI Kramm, I Herrmann-Geppert… - Journal of the …, 2016 - ACS Publications
Today, most metal and nitrogen doped carbon catalysts for ORR reveal a heterogeneous
composition. This can be reasoned by a nonoptimized precursor composition and various …

A review of the stability and durability of non-precious metal catalysts for the oxygen reduction reaction in proton exchange membrane fuel cells

D Banham, S Ye, K Pei, J Ozaki, T Kishimoto… - Journal of Power …, 2015 - Elsevier
A major hurdle to the widespread commercialization of proton exchange membrane fuel
cells (PEMFCs) is the high loading of noble metal (Pt/Pt-alloy) catalyst at the cathode, which …

Transition metal–nitrogen–carbon nanostructured catalysts for the oxygen reduction reaction: from mechanistic insights to structural optimization

M Shen, C Wei, K Ai, L Lu - Nano Research, 2017 - Springer
Accelerating the rate-limiting oxygen reduction reaction (ORR) at the cathode remains the
foremost issue for the commercialization of fuel cells. Transition metal–nitrogen–carbon (M …

Boosting bifunctional oxygen electrolysis for N‐doped carbon via bimetal addition

J Wang, F Ciucci - Small, 2017 - Wiley Online Library
The addition of transition metals, even in a trace amount, into heteroatom‐doped carbon (M‐
N/C) is intensively investigated to further enhance oxygen reduction reaction (ORR) activity …

Active sites and factors influencing them for efficient oxygen reduction reaction in metal-N coordinated pyrolyzed and non-pyrolyzed catalysts: a review

K Singh, F Razmjooei, JS Yu - Journal of Materials Chemistry A, 2017 - pubs.rsc.org
With increasing demand for clean energy and approaching commercialization of polymer
electrolyte membrane fuel cells (PEMFCs), replacing expensive Pt-based cathode catalysts …

Clarifying the critical roles of iron in boosting oxygen reduction: Single Fe atoms anchored on carbon vacancies as efficient active sites

F Tan, W Li, J Wang, C Min, Z Li, B Zhang… - Applied Catalysis B …, 2022 - Elsevier
Due to highly heterogeneity of pyrolyzed transition metal-nitrogen-carbon (MNC) catalyst,
elucidating mechanisms of roles of metal in enhancing oxygen reduction reaction (ORR) is …

PEM fuel cell electrocatalysts based on transition metal macrocyclic compounds

Y Liu, X Yue, K Li, J Qiao, DP Wilkinson… - Coordination Chemistry …, 2016 - Elsevier
This paper provides a comprehensive overview of the current state of development of
transition metal macrocyclic (TMM) complex-based electrocatalysts used in oxygen …