Organic xanthates are broadly applied as synthetic intermediates and bioactive molecules in
synthetic chemistry. Electrophilic xanthylation represents a promising approach but has …

A simple, efficient, and practical method for the synthesis of S-quinolyl xanthates was
developed via Ts2O-promoted deoxygenative C–H dithiocarbonation of quinoline N-oxides …

Diethyl acetamidomalonate (DEAM) has been widely used for the synthesis of α-amino
acids via C-alkylation under basic conditions followed by hydrolysis/decarboxylation. In …

An environmentally benign protocol that provides various S-quinolyl xanthates via a ball
milling enabled cross coupling reaction of haloquinolines and readily available potassium O …

A copper-catalyzed efficient method for the synthesis of a diverse variety of substituted N-
aryl pyrazoles from readily available α, β-alkynic N-tosyl hydrazones and diaryliodonium …

Diaryliodonium salts have become widely recognized as arylating agents in the last two
decades. Both, symmetrical and unsymmetrical forms of these salts serve as effective …

Most existing methods for the synthesis of alkyl aryl thioethers require the use of mercaptans
as the starting materials, which comes with practical limitations. Reactions of diaryliodonium …

Visible‐light‐activated organic reactions unlock novel avenues for complex molecular
transformations, impossible under standard “thermal” conditions, which makes them …

We demonstrate (1) detectable halogen bonding is not critical for enabling light-driven
radical generation from diaryliodonium salts and (2) radicals generated by this route can be …

Electroorganic synthesis is generally considered to be a green alternative to conventional
redox reactions. Electrochemical reductions, however, are less advantageous in terms of …