Controlling the metal–ligand coordination environment of manganese phthalocyanine in 1D–2D heterostructure for enhancing nitrate reduction to ammonia

A Adalder, S Paul, N Barman, A Bera, S Sarkar… - ACS …, 2023 - ACS Publications
Eight-electron nitrate reduction (NO3RR) offers a cost-effective and environmentally friendly
route of ammonia production and wastewater remediation. However, identification and …

Iron phthalocyanine hollow architecture enabled ammonia production via nitrate reduction to achieve 100% Faradaic efficiency

S Sarkar, A Adalder, S Paul, S Kapse, R Thapa… - Applied Catalysis B …, 2024 - Elsevier
Abstract Eight electron nitrate (NO 3–) reduction to ammonia (NH 3) offers a cost–effective
and energy efficient route than the Haber–Bosch process. The state of art electrocatalysts for …

Catalytic reactivity descriptors of metal‐nitrogen‐doped carbon catalysts for electrocatalysis

H Liu, J Li, J Arbiol, B Yang, P Tang - EcoEnergy, 2023 - Wiley Online Library
Metal‐nitrogen‐doped carbon material have sparked enormous attentions as they show
excellent electrocatalytic performance and provide a prototype for mechanistic …

Engineering hydrophobic–aerophilic interfaces to boost N 2 diffusion and reduction through functionalization of fluorine in second coordination spheres

S Bhardwaj, SK Das, A Biswas, S Kapse, R Thapa… - Chemical …, 2023 - pubs.rsc.org
Ammonia is a crucial biochemical raw material for nitrogen containing fertilizers and a
hydrogen energy carrier obtained from renewable energy sources. Electrocatalytic ammonia …

Fe (TCNQ) 2 nanorod arrays: an efficient electrocatalyst for electrochemical ammonia synthesis via the nitrate reduction reaction

N Mukherjee, A Adalder, N Barman, R Thapa… - Journal of Materials …, 2024 - pubs.rsc.org
The electrochemical reduction of nitrate to ammonia (NO3RR) catalyzed by metal organic
frameworks (MOFs) is a promising and efficient method for reducing nitrate pollution in water …

Optimizing CO2RR selectivity on single atom catalysts using graphical construction and identification of energy descriptor

A Tripathi, R Thapa - Carbon, 2023 - Elsevier
The electrocatalytic reduction of CO 2 (CO 2 RR) into value-added hydrocarbons is limited
due to high limiting potential (UL) and competing hydrogen evolution reaction (HER). To find …

Bridging Together Theoretical and Experimental Perspectives in Single‐Atom Alloys for Electrochemical Ammonia Production

MI Ahmed, C Wang, Y Zhao, CI Sathish, Z Lei, L Qiao… - Small, 2024 - Wiley Online Library
Ammonia is an essential commodity in the food and chemical industry. Despite the energy‐
intensive nature, the Haber–Bosch process is the only player in ammonia production at …

Beyond Conventional Catalysts: Monoelemental Tellurium as a Game Changer for Piezo‐Driven Hydrogen Evolution

HK Mishra, Ankush, N Barman, B Mondal, M Jha… - Small, 2024 - Wiley Online Library
The increasing demand for clean hydrogen production over fossil fuels necessitates the
development of sustainable piezoelectrochemical methods that can overcome the limitations …

C2 Product Formation over the C1 Product and HER on the 111 Plane of Specific Cu Alloy Nanoparticles Identified through Multiparameter Optimization

A Iqbal, A Tripathi, R Thapa - Inorganic Chemistry, 2024 - ACS Publications
C2 products are more desirable than C1 products during CO2 electroreduction (CO2ER)
because the former possess higher energy density and greater industrial value. For CO2ER …

Boosting Selective Nitrogen Oxidation to Nitric Acid by Synergizing Cobalt Phthalocyanine on Carbon Nitride Surface

S Paul, A Adalder, N Barman, R Thapa… - Advanced Functional …, 2024 - Wiley Online Library
The Ostwald process, which is producing HNO3 for commercial use, involves the catalytic
oxidation of NH3 and a series of chemical reactions conducted under severe operating …