Precision polymer synthesis by controlled radical polymerization: Fusing the progress from polymer chemistry and reaction engineering

YN Zhou, JJ Li, TT Wang, YY Wu, ZH Luo - Progress in Polymer Science, 2022 - Elsevier
During the first 100 years of polymer science, controlled radical polymerization (also
recommended as reversible deactivation radical polymerization) is undoubtedly a …

A guide to the synthesis of block copolymers using reversible-addition fragmentation chain transfer (RAFT) polymerization

DJ Keddie - Chemical Society Reviews, 2014 - pubs.rsc.org
The discovery of reversible-deactivation radical polymerization (RDRP) has provided an
avenue for the synthesis of a vast array of polymers with a rich variety of functionality and …

[HTML][HTML] Living radical polymerization by the RAFT process–a third update

G Moad, E Rizzardo, SH Thang - Australian Journal of Chemistry, 2012 - CSIRO Publishing
This paper provides a third update to the review of reversible deactivation radical
polymerization (RDRP) achieved with thiocarbonylthio compounds (ZC (= S) SR) by a …

RAFT agent design and synthesis

DJ Keddie, G Moad, E Rizzardo, SH Thang - Macromolecules, 2012 - ACS Publications
This Perspective reviews the design and synthesis of RAFT agents. First, we briefly detail the
basic design features that should be considered when selecting a RAFT agent or macro …

Controlled/living radical polymerization: Features, developments, and perspectives

WA Braunecker, K Matyjaszewski - Progress in polymer science, 2007 - Elsevier
Recent mechanistic developments in the field of controlled/living radical polymerization
(CRP) are reviewed. Particular emphasis is placed on structure–reactivity correlations and …

Bioapplications of RAFT polymerization

C Boyer, V Bulmus, TP Davis, V Ladmiral, J Liu… - Chemical …, 2009 - ACS Publications
A living radical polymerization (LRP) is a free radical polymerization that aims at displaying
living character,(ie, does not terminate or transfer and is able to continue polymerization …

Living radical polymerization by the RAFT process

G Moad, E Rizzardo, SH Thang - Australian journal of chemistry, 2005 - CSIRO Publishing
This paper presents a review of living radical polymerization achieved with thiocarbonylthio
compounds [ZC (= S) SR] by a mechanism of reversible addition–fragmentation chain …

[HTML][HTML] Radical addition–fragmentation chemistry in polymer synthesis

G Moad, E Rizzardo, SH Thang - Polymer, 2008 - Elsevier
This review traces the development of addition–fragmentation chain transfer agents and
related ring-opening monomers highlighting recent innovation in these areas. The major …

Complex polymer architectures via RAFT polymerization: From fundamental process to extending the scope using click chemistry and nature's building blocks

A Gregory, MH Stenzel - Progress in Polymer Science, 2012 - Elsevier
Reversible addition fragmentation chain transfer (RAFT) polymerization has made a huge
impact in macromolecular design. The first block copolymers were described early on …

Living radical polymerization by the RAFT process–a second update

G Moad, E Rizzardo, SH Thang - Australian journal of chemistry, 2009 - CSIRO Publishing
This paper provides a second update to the review of reversible deactivation radical
polymerization achieved with thiocarbonylthio compounds (ZC (= S) SR) by a mechanism of …