The dawn of functional organoarsenic chemistry

H Imoto, K Naka - Chemistry–A European Journal, 2019 - Wiley Online Library
Organoarsenic chemistry was actively studied until the middle of 20th century. Although
various properties of organoarsenic compounds have been computationally predicted, for …

Recent progress on arsenic-containing functional polymers

H Imoto, K Naka - Polymer, 2022 - Elsevier
Heteroatom-fused polymer materials can realize structures, functions, and reactivities that
cannot be achieved with polymers that lack fused heteroatoms in their structure. Although …

KiMoPack: A python Package for Kinetic Modeling of the Chemical Mechanism

C Müller, T Pascher, A Eriksson… - The Journal of …, 2022 - ACS Publications
Herein, we present KiMoPack, an analysis tool for the ki netic mo deling of transient
spectroscopic data. KiMoPack enables a state-of-the-art analysis routine including data …

Overview of the Synthesis and Catalytic Reactivity of Transition Metal Complexes Based on C═ P Bond Systems

A Ziółkowska, J Doroszuk, Ł Ponikiewski - Organometallics, 2023 - ACS Publications
This report provides an overview of the use of phosphaalkenes (C═ P) in syntheses of
various complexes. Going through successive complexes containing the d-block metals, we …

Probing the Hidden Photoisomerization of a Symmetric Phosphaalkene Switch

R Deka, J Steen, MF Hilbers… - Angewandte Chemie …, 2024 - Wiley Online Library
In this study, we present the synthesis and analysis of a novel, air‐stable, and solvent‐
resistant phosphaalkene switch. Using this symmetric switch, we have demonstrated …

Expanding the Landscape of Phosphorous‐Based Open Shell Species: Stable Mono‐, Di‐, and Trianionic Radicals Based on a Contorted Triphosphaalkene

MA Ansari, R Deka, A Thapper… - Angewandte Chemie …, 2024 - Wiley Online Library
The stepwise reduction of the highly contorted truxene‐based triphosphaalkene 1 using
KC8 led to the isolation of mono‐, di‐, and tri‐anionic species. The solid‐state molecular …

Heavier pnictogens–treasures for optical electronic and reactivity tuning

JP Green, JAL Wells, A Orthaber - Dalton Transactions, 2019 - pubs.rsc.org
We highlight recent advances in organopnictogen chemistry contrasting the properties of
lighter and heavier pnictogens. Exploring new bonding situations, discovering …

One, Two Three–Phosphaalkene Decoration Tailoring Solubility and Electronic Properties of Truxene‐Based Electron Acceptors

MA Shameem, JAL Wells, AK Gupta… - … –A European Journal, 2023 - Wiley Online Library
We report the functionalization and deplanarization of truxenes using pnictaalkene
fragments. Selective introduction of one, two, or three Mes*‐Pn fragments provides up to …

Main Group Pentafulvenes: Challenges and Opportunities in Heavy Main Group Isolobal Substitution of Pentafulvene

T Bhowmick, A Orthaber - ChemPhysChem, 2024 - Wiley Online Library
Heterofulvenes based on isolobal substitution of carbon fragments by (heavier) main group
motifs provide a rich source of structurally interesting building blocks with electronic …

Core and double bond functionalisation of cyclopentadithiophene-phosphaalkenes

JAL Wells, MA Shameem, AK Gupta… - Inorganic Chemistry …, 2020 - pubs.rsc.org
The heterofulvenoid cyclopentadithiophene-phosphaalkene is a versatile building block for
opto-electronic tuning with donor and acceptor moieties. Both the annulated thienyl rings …