Surface‐mounted metal–organic frameworks: crystalline and porous molecular assemblies for fundamental insights and advanced applications
Metal–organic frameworks (MOFs) are crystalline coordination polymers, assembled from
inorganic nodes connected by organic linker molecules. An enormous surface area, huge …
inorganic nodes connected by organic linker molecules. An enormous surface area, huge …
Light‐driven actuation in synthetic polymers: a review from fundamental concepts to applications
Light‐driven actuation of synthetic polymers is an emerging field of interest because it offers
simple remote addressing without complicated hydraulic, electric, or magnetic systems …
simple remote addressing without complicated hydraulic, electric, or magnetic systems …
Polymer mechanochromism from force-tuned excited-state intramolecular proton transfer
Real-time monitoring of strain/stress in polymers is a big challenge to date. Herein, we for
the first time report an ESIPT (excited-state intramolecular proton transfer)-based …
the first time report an ESIPT (excited-state intramolecular proton transfer)-based …
Photochemistry of azobenzene-containing polymers
GS Kumar, DC Neckers - Chemical Reviews, 1989 - ACS Publications
Photochemical reactions which occur in smallmole-cules can also be induced to occur in
macromolecules. Though, in macromolecular environments there are constraints which are …
macromolecules. Though, in macromolecular environments there are constraints which are …
Small-molecule-directed nanoparticle assembly towards stimuli-responsive nanocomposites
Y Zhao, K Thorkelsson, AJ Mastroianni, T Schilling… - Nature materials, 2009 - nature.com
Precise control of the spatial organization of nanoscopic building blocks, such as
nanoparticles, over multiple length scales is a bottleneck in the 'bottom-up'generation of …
nanoparticles, over multiple length scales is a bottleneck in the 'bottom-up'generation of …
Recent developments in aromatic azo polymers research
S Xie, A Natansohn, P Rochon - Chemistry of Materials, 1993 - ACS Publications
The photochemical and thermal cis-to-trans isomerization of aromatic azo groups covalently
bonded within polymers and its practical consequences as well as some other recent …
bonded within polymers and its practical consequences as well as some other recent …
Photoresponsive crown ethers. 2. Photocontrol of ion extraction and ion transport by a bis (crown ether) with a butterfly-like motion
S Shinkai, T Nakaji, T Ogawa… - Journal of the …, 1981 - ACS Publications
A photoresponsive bis (crown ether) with an azo linkage (1) was synthesized, trans-1 was
isomerized by UV light to cis-1 and cis-1 was isomerized thermally to trans-1, the …
isomerized by UV light to cis-1 and cis-1 was isomerized thermally to trans-1, the …
Mechanism of optically inscribed high-efficiency diffraction gratings in azo polymer films
CJ Barrett, AL Natansohn… - The Journal of Physical …, 1996 - ACS Publications
A series of amorphous azobenzene-containing polymers were cast as thin films and shown
to produce both reversible volume diffraction gratings and high-efficiency surface gratings by …
to produce both reversible volume diffraction gratings and high-efficiency surface gratings by …
Azo polymers for reversible optical storage. 1. Poly [4'-[[2-(acryloyloxy) ethyl] ethylamino]-4-nitroazobenzene]
A Natansohn, P Rochon, J Gosselin, S Xie - Macromolecules, 1992 - ACS Publications
Poly [4'-[[2-(acryloyloxy) ethyl] ethylamino]-4-nitroazobenzene](pDRIA) is used as an
example to demonstratethe ability of amorphous high-Tg azoaromatic-containing polymers …
example to demonstratethe ability of amorphous high-Tg azoaromatic-containing polymers …
On measuring the distribution of local free volume in glassy polymers by photochromic and fluorescence techniques
JG Victor, JM Torkelson - Macromolecules, 1987 - ACS Publications
Ageneral technique, based on photoisomerization of photochromic and fluorescent probe
molecules having no net dipole moment, has been devised for measuring the distribution of …
molecules having no net dipole moment, has been devised for measuring the distribution of …