Surface‐mounted metal–organic frameworks: crystalline and porous molecular assemblies for fundamental insights and advanced applications

L Heinke, C Wöll - Advanced Materials, 2019 - Wiley Online Library
Metal–organic frameworks (MOFs) are crystalline coordination polymers, assembled from
inorganic nodes connected by organic linker molecules. An enormous surface area, huge …

Light‐driven actuation in synthetic polymers: a review from fundamental concepts to applications

MRA Bhatti, A Kernin, M Tausif, H Zhang… - Advanced Optical …, 2022 - Wiley Online Library
Light‐driven actuation of synthetic polymers is an emerging field of interest because it offers
simple remote addressing without complicated hydraulic, electric, or magnetic systems …

Polymer mechanochromism from force-tuned excited-state intramolecular proton transfer

H Hu, X Cheng, Z Ma, RP Sijbesma… - Journal of the American …, 2022 - ACS Publications
Real-time monitoring of strain/stress in polymers is a big challenge to date. Herein, we for
the first time report an ESIPT (excited-state intramolecular proton transfer)-based …

Photochemistry of azobenzene-containing polymers

GS Kumar, DC Neckers - Chemical Reviews, 1989 - ACS Publications
Photochemical reactions which occur in smallmole-cules can also be induced to occur in
macromolecules. Though, in macromolecular environments there are constraints which are …

Small-molecule-directed nanoparticle assembly towards stimuli-responsive nanocomposites

Y Zhao, K Thorkelsson, AJ Mastroianni, T Schilling… - Nature materials, 2009 - nature.com
Precise control of the spatial organization of nanoscopic building blocks, such as
nanoparticles, over multiple length scales is a bottleneck in the 'bottom-up'generation of …

Recent developments in aromatic azo polymers research

S Xie, A Natansohn, P Rochon - Chemistry of Materials, 1993 - ACS Publications
The photochemical and thermal cis-to-trans isomerization of aromatic azo groups covalently
bonded within polymers and its practical consequences as well as some other recent …

Photoresponsive crown ethers. 2. Photocontrol of ion extraction and ion transport by a bis (crown ether) with a butterfly-like motion

S Shinkai, T Nakaji, T Ogawa… - Journal of the …, 1981 - ACS Publications
A photoresponsive bis (crown ether) with an azo linkage (1) was synthesized, trans-1 was
isomerized by UV light to cis-1 and cis-1 was isomerized thermally to trans-1, the …

Mechanism of optically inscribed high-efficiency diffraction gratings in azo polymer films

CJ Barrett, AL Natansohn… - The Journal of Physical …, 1996 - ACS Publications
A series of amorphous azobenzene-containing polymers were cast as thin films and shown
to produce both reversible volume diffraction gratings and high-efficiency surface gratings by …

Azo polymers for reversible optical storage. 1. Poly [4'-[[2-(acryloyloxy) ethyl] ethylamino]-4-nitroazobenzene]

A Natansohn, P Rochon, J Gosselin, S Xie - Macromolecules, 1992 - ACS Publications
Poly [4'-[[2-(acryloyloxy) ethyl] ethylamino]-4-nitroazobenzene](pDRIA) is used as an
example to demonstratethe ability of amorphous high-Tg azoaromatic-containing polymers …

On measuring the distribution of local free volume in glassy polymers by photochromic and fluorescence techniques

JG Victor, JM Torkelson - Macromolecules, 1987 - ACS Publications
Ageneral technique, based on photoisomerization of photochromic and fluorescent probe
molecules having no net dipole moment, has been devised for measuring the distribution of …