Chemodivergent reactions

IP Beletskaya, C Nájera, M Yus - Chemical Society Reviews, 2020 - pubs.rsc.org
An important strategy for the efficient generation of diversity in molecular structures is the
utilization of common starting materials in chemodivergent transformations. The most …

Synthesis of 4‐(Trifluoromethyl)‐2, 3‐Dihydrothiazoles from α‐Enolic Dithioesters and Imidoyl Sulfoxonium Ylides

D Yang, Y Wang, T Wang, Q Dou… - Advanced Synthesis …, 2023 - Wiley Online Library
Abstract The synthesis of 4‐(trifluoromethyl)‐2, 3‐dihydrothiazoles from α‐enolic dithioesters
and imidoyl sulfoxonium ylides has been achieved under thermal conditions. This …

A decade update on the application of β-oxodithioesters in heterocyclic synthesis

ZB Dong, Z Gong, Q Dou, B Cheng… - Organic & Biomolecular …, 2023 - pubs.rsc.org
The diversified synthesis of heterocyclic compounds has always been one of the popular
subjects of organic chemistry. To this end, great efforts have been devoted to developing …

Visible light-induced radical cyclization of o-alkenyl aromatic isocyanides with thioethers: direct synthesis of 2-thioquinolines

YX Liang, Y Gong, XC Xu, M Yang… - Organic Chemistry …, 2024 - pubs.rsc.org
A novel visible-light-induced photoredox-catalyzed regioselective radical cyclization
reaction of isocyanides with thioethers has been developed for the first time. This reaction …

Synthesis of 1, 3, 4-Thiadiazoles and 1, 4, 2-Oxathiazoles from α-Enolic Dithioesters and Active 1, 3-Dipoles

B Cheng, H Li, J Sun, X Zhang, Y He… - The Journal of …, 2021 - ACS Publications
The synthesis of two kinds of five-membered organosulfur heterocycles (ie, 1, 4, 2-
oxathiazoles and 1, 3, 4-thiadiazoles) from α-enolic dithioesters with active 1, 3-dipoles …

Rhodium (III)-catalyzed chemodivergent annulations between phenyloxazoles and diazos via C–H activation

X Zhang, P Wang, L Zhu, B Chen - Chinese Chemical Letters, 2021 - Elsevier
Acid-controlled, chemodivergent and redox-neutral annulations for the synthesis of
isocoumarins and isoquinolinones have been realized via Rh (III)-catalyzed Csingle bondH …

p-Toluenesulfonic acid-catalyzed metal-free formal [4+ 1] heteroannulation via NH/OH/SH functionalization: One-pot access to 2-aryl/hetaryl/alkyl benzazole …

A Srivastava, G Shukla, MS Singh - Tetrahedron, 2017 - Elsevier
A concise and direct one-pot [4+ 1] synthetic strategy for the construction of 2-substituted
benzazoles such as benzoxazoles and benzothiazoles has been disclosed in high yields …

Microwave-assisted, regioselective one-pot synthesis of quinolines and bis-quinolines catalyzed by Bi (III) immobilized on triazine dendrimer stabilized magnetic …

B Asadi, A Landarani-Isfahani… - Tetrahedron letters, 2017 - Elsevier
Abstract Fe 3 O 4-TDSN-Bi (III) was utilized as an efficient and reusable catalyst for the
regioselective one-pot synthesis of quinoline derivatives from arylamines, arylaldehydes …

Switching selectivity of α-enolic dithioesters: One pot access to functionalized 1, 2-and 1, 3-dithioles

S Koley, T Chanda, S Samai… - The Journal of Organic …, 2016 - ACS Publications
An operationally simple cascade protocol has been developed for the construction of 1, 2-
and 1, 3-dithiole derivatives from α-enolic dithioesters. 1, 2-Dithioles are achieved by the …

Convenient Synthesis of Quinoline‐4‐carboxylate Derivatives through the Bi(OTf)3‐Catalyzed Domino Cyclization/Esterification Reaction of Isatins with Enaminones …

P Zhou, B Hu, Y Wang, Q Zhang, X Li… - European Journal of …, 2018 - Wiley Online Library
An efficient Bi (OTf) 3‐catalyzed method for the synthesis of quinoline‐4‐carboxylates
through a domino cyclization/esterification reaction of isatins with enaminones in alcohols is …