Atomically precise clusters of noble metals: emerging link between atoms and nanoparticles

I Chakraborty, T Pradeep - Chemical reviews, 2017 - ACS Publications
Atomically precise pieces of matter of nanometer dimensions composed of noble metals are
new categories of materials with many unusual properties. Over 100 molecules of this kind …

Chiral inorganic nanostructures

W Ma, L Xu, AF de Moura, X Wu, H Kuang, C Xu… - Chemical …, 2017 - ACS Publications
The field of chiral inorganic nanostructures is rapidly expanding. It started from the
observation of strong circular dichroism during the synthesis of individual nanoparticles …

Au 25 (SR) 18: the captain of the great nanocluster ship

X Kang, H Chong, M Zhu - Nanoscale, 2018 - pubs.rsc.org
Noble metal nanoclusters are in the intermediate state between discrete atoms and
plasmonic nanoparticles and are of significance due to their atomically accurate structures …

The gold–sulfur interface at the nanoscale

H Häkkinen - Nature chemistry, 2012 - nature.com
Thiolate-protected gold surfaces and interfaces, relevant for self-assembled monolayers of
organic molecules on gold, for passivated gold nanoclusters and for molecule–gold …

Atomically precise metal nanoclusters: stable sizes and optical properties

R Jin - Nanoscale, 2015 - pubs.rsc.org
Controlling nanoparticles with atomic precision has long been a major dream of
nanochemists. Breakthroughs have been made in the case of gold nanoparticles, at least for …

Roles of thiolate ligands in the synthesis, properties and catalytic application of gold nanoclusters

RR Nasaruddin, T Chen, N Yan, J Xie - Coordination Chemistry Reviews, 2018 - Elsevier
Abstract Ultrasmall (< 2 nm) ligand-protected metal nanoclusters (NCs) have been an
emerging class of functional materials with rich coordination chemistry, finding increasing …

Chirality and surface bonding correlation in atomically precise metal nanoclusters

Y Li, T Higaki, X Du, R Jin - Advanced Materials, 2020 - Wiley Online Library
Chirality is ubiquitous in nature and occurs at all length scales. The development of
applications for chiral nanostructures is rising rapidly. With the recent achievements of …

Chirality in thiolate-protected gold clusters

S Knoppe, T Bürgi - Accounts of chemical research, 2014 - ACS Publications
Conspectus Over recent years, research on thiolate-protected gold clusters Au m (SR) n has
gained significant interest. Milestones were the successful determination of a series of …

Transformation of atomically precise nanoclusters by ligand-exchange

X Kang, M Zhu - Chemistry of Materials, 2019 - ACS Publications
Owing to their atomically precise structures, metal nanoclusters have always served as
model molecular tools to dissect nanoparticle surface chemistry and to investigate structure …

Chiral spectroscopy of nanostructures

J Kwon, KH Park, WJ Choi, NA Kotov… - Accounts of Chemical …, 2023 - ACS Publications
Conspectus Chirality is ubiquitous in the universe and in living creatures over detectable
length scales from the subatomic to the galactic, as exemplified in the two extremes by …