Octahedral cluster complexes of molybdenum and tungsten,[M6X8Y6] n−(M= Mo, W; X, Y=
Cl, Br, I), are promising active components in various fields, including biomedicine and solar …

This contribution describes a novel method for the detection of trace amounts of
trinitrotoluene (TNT) using a cluster of hexamolybdenum with general formula [Mo6Cl14] 2 …

Reduction of TaBr5 with Ga in the presence of KBr in a sealed borosilicate ampule at 400°,
followed by aqueous Soxhlet extraction and addition of stannous bromide and hydrobromic …

The molybdenum cluster [Mo6Cl14] 2− is a fluorescent component with potential for use in
cell labelling and pharmacology. Biological safety and antiviral properties of the cluster are …

Charge-assisted hydrogen bonding plays a significant role in the crystal structures of
solvates of ionic compounds, especially when the cation or cations are primary ammonium …

Tungsten tetrachloride is the most synthetically useful binary tungsten chloride. This chapter
reports on the convenient preparations of WCl4 from WCl6 in a crystalline, edge‐sharing …

Triangular tritungsten compounds with one or two face‐bridging chalcogenides are well
known. Mild main group metal reductants such as mercury, bismuth, antimony, gallium, and …

Всё большее внимание научной общественности привлекают октаэдрические
галогенидные кластерные комплексы вольфрама с ядром {W6X8} 4+(X= Cl, Br, I) …

Octahedral hexatantalum halide clusters usually exist as extended structures of the form Ta6
(μ‐X) 12X2. These clusters consist of six tantalums linked through Ta‐Ta bonding to form a …

Solid state reduction of NbCl 5, with excess NaCl, by Ga 2 Cl 4 under lower-temperature
(175°) kinetic control yields a brown powder from which the green, incomplete cubane …