Fe (II) redox chemistry in the environment

J Huang, A Jones, TD Waite, Y Chen, X Huang… - Chemical …, 2021 - ACS Publications
Iron (Fe) is the fourth most abundant element in the earth's crust and plays important roles in
both biological and chemical processes. The redox reactivity of various Fe (II) forms has …

An overview of the role of goethite surfaces in the environment

H Liu, T Chen, RL Frost - Chemosphere, 2014 - Elsevier
Goethite, one of the most thermodynamically stable iron oxides, has been extensively
researched especially the structure (including surface structure), the adsorption capacity to …

Effect of solution and solid-phase conditions on the Fe (II)-accelerated transformation of ferrihydrite to lepidocrocite and goethite

DD Boland, RN Collins, CJ Miller… - … science & technology, 2014 - ACS Publications
Aqueous ferrous iron (Fe (II)) accelerates the transformation of ferrihydrite into secondary,
more crystalline minerals however the factors controlling the rate and, indeed, the …

Atom exchange between aqueous Fe (II) and goethite: an Fe isotope tracer study

RM Handler, BL Beard, CM Johnson… - … science & technology, 2009 - ACS Publications
The reaction of aqueous Fe (II) with Fe (III) oxides is a complex process, comprising sorption,
electron transfer, and in some cases, reductive dissolution and transformation to secondary …

Aquatic environmental nanoparticles

NS Wigginton, KL Haus, MF Hochella Jr - Journal of environmental …, 2007 - pubs.rsc.org
Researchers are now discovering that naturally occurring environmental nanoparticles can
play a key role in important chemical characteristics and the overall quality of natural and …

Visible light induced photocatalytic degradation of rhodamine B on one-dimensional iron oxide particles

X Zhou, H Yang, C Wang, X Mao, Y Wang… - The Journal of …, 2010 - ACS Publications
Visible light (λ> 420 nm) induced photocatalytic degradation of rhodamine B (RhB) in the
presence of H2O2 by one-dimensional (1D) nanorods of goethite (α-FeOOH) and hematite …

Organic matter and iron oxide nanoparticles: aggregation, interactions, and reactivity

AM Vindedahl, JH Strehlau, WA Arnold… - Environmental Science …, 2016 - pubs.rsc.org
Understanding the fate and transport of engineered and naturally-occurring nanoparticles is
vital to predicting their ecological and toxicological impacts. Much of the current literature …

Electrochemical analyses of redox-active iron minerals: a review of nonmediated and mediated approaches

M Sander, TB Hofstetter, CA Gorski - Environmental science & …, 2015 - ACS Publications
Redox-active minerals are ubiquitous in the environment and are involved in numerous
electron transfer reactions that significantly affect biogeochemical processes and cycles as …

Thermodynamic Characterization of Iron Oxide–Aqueous Fe2+ Redox Couples

CA Gorski, R Edwards, M Sander… - … science & technology, 2016 - ACS Publications
Iron is present in virtually all terrestrial and aquatic environments, where it participates in
redox reactions with surrounding metals, organic compounds, contaminants, and …

Ferrous Iron Oxidation under Varying pO2 Levels: The Effect of Fe(III)/Al(III) Oxide Minerals and Organic Matter

C Chen, A Thompson - Environmental Science & Technology, 2018 - ACS Publications
Abiotic Fe (II) oxidation by O2 commonly occurs in the presence of mineral sorbents and
organic matter (OM) in soils and sediments; however, this tertiary system has rarely been …