Value-added processing of crude glycerol into chemicals and polymers

X Luo, X Ge, S Cui, Y Li - Bioresource Technology, 2016 - Elsevier
Crude glycerol is a low-value byproduct which is primarily obtained from the biodiesel
production process. Its composition is significantly different from that of pure glycerol. Crude …

Heterogeneous catalysis for bio-based polyester monomers from cellulosic biomass: advances, challenges and prospects

R De Clercq, M Dusselier, BF Sels - Green Chemistry, 2017 - pubs.rsc.org
It is a 21st century challenge to develop a more sustainable chemical industry where fossil-
based resources are, where possible, preferentially replaced by renewable alternatives. Bio …

Biorefinery concepts in comparison to petrochemical refineries

E de Jong, G Jungmeier - Industrial biorefineries & white biotechnology, 2015 - Elsevier
Biorefinery, the sustainable processing of biomass into a spectrum of marketable products
and energy, is compared to petrochemical refineries. The economic value of biomass …

Phenomena affecting catalytic reactions at solid–liquid interfaces

C Sievers, Y Noda, L Qi, EM Albuquerque… - ACS …, 2016 - ACS Publications
Interest in liquid-phase reactions over heterogeneous catalysts is growing rapidly, partially
because of the desire to find efficient methods for biomass conversion to renewable fuels …

Regulating the competitive reaction pathway in glycerol conversion to lactic acid/glycolic acid selectively

S Xu, Q Tian, Y Xiao, W Zhang, S Liao, J Li, C Hu - Journal of Catalysis, 2022 - Elsevier
The numerous parallel reactions in glycerol conversion substantially challenge the effective
synthesis of target chemical from oversupplied glycerol. Herein, we intensively studied the …

Current and future trends for crude glycerol upgrading to high value-added products

MH Moklis, S Cheng, JS Cross - Sustainability, 2023 - mdpi.com
Crude glycerol is the main byproduct of biodiesel manufacturing from oleaginous crops and
other biomass-derived oils. Approximately 10% crude glycerol is produced with every batch …

Lactide synthesis and chirality control for polylactic acid production

P Van Wouwe, M Dusselier, E Vanleeuw… - …, 2016 - Wiley Online Library
Polylactic acid (PLA) is a very promising biodegradable, renewable, and biocompatible
polymer. Aside from its production, its application field is also increasing, with use not only in …

Production of lactic acid from glycerol via chemical conversion using solid catalyst: A review

N Razali, AZ Abdullah - Applied Catalysis A: General, 2017 - Elsevier
The production of lactic acid from glycerol has been receiving a lot of attention due to the
efficient roles of glycerol as raw material in producing various useful chemicals. Selective …

The conversion of glycerol to lactic acid catalyzed by ZrO2-supported CuO catalysts

GY Yang, YH Ke, HF Ren, CL Liu, RZ Yang… - Chemical Engineering …, 2016 - Elsevier
Zirconia-supported copper oxide catalysts with various compositions were prepared and
characterized by atomic absorption spectroscopy, N 2 physical adsorption, temperature …

A switchable route to valuable commodity chemicals from glycerol via electrocatalytic oxidation with an earth abundant metal oxidation catalyst

CH Lam, AJ Bloomfield, PT Anastas - Green Chemistry, 2017 - pubs.rsc.org
Electrocatalytic upgrading of glycerol to value-added commodity is demonstrated using an
ultralow loading of a cobalt-based oxidation catalyst at 16 μg cm− 2. Reactions take place …