Assessing cooperativity in supramolecular systems

LKS von Krbek, CA Schalley… - Chemical Society Reviews, 2017 - pubs.rsc.org
This tutorial review summarises different aspects of cooperativity in supramolecular
complexes. We propose a systematic categorisation of cooperativity into cooperative …

[HTML][HTML] The effects of layered nanoparticles and their properties on the molecular aggregation of organic dyes

J Bujdák - Journal of Photochemistry and Photobiology C …, 2018 - Elsevier
The phenomenon of metachromasia, which is related to molecular aggregation, leads to
significant changes in the photophysical properties of dyes. This review summarizes existing …

Towards quantifying the role of hydrogen bonding within amphiphile self-association and resultant aggregate formation

LJ White, NJ Wells, LR Blackholly, HJ Shepherd… - Chemical …, 2017 - pubs.rsc.org
Herein, we present a series of five tetrabutylammonium (TBA) sulfonate–urea amphiphilic
salts. In solution these amphiphilic salts have been shown to form a variety of self …

Liberating the Anion: Evaluating Weakly Coordinating Cations

SH Dempsey, SR Kass - The Journal of Organic Chemistry, 2022 - ACS Publications
A series of commonly used weakly coordinating cations (WCCs) including
tetraalkylammonium, bis (triphenylphosphine) iminium (PPN), P2 and P5 phosphazenium …

Quantifying Intermolecular Interactions in Asymmetric Peptide Organocatalysis as a Key toward Understanding Selectivity

J Nowag, M Brauser, L Steuernagel… - Journal of the …, 2023 - ACS Publications
The kinetic resolution of trans-cyclohexane-1, 2-diol with a lipophilic oligopeptide catalyst
shows extraordinary selectivities. To improve our understanding of the factors governing …

Towards the Prediction of Global Solution State Properties for Hydrogen Bonded, Self‐Associating Amphiphiles

LJ White, SN Tyuleva, B Wilson… - … A European Journal, 2018 - Wiley Online Library
Through this extensive structure–property study we show that critical micelle concentration
correlates with self‐associative hydrogen bond complex formation constant, when combined …

Towards the application of supramolecular self-associating amphiphiles as next-generation delivery vehicles

LJ White, JE Boles, KLF Hilton, RJ Ellaby, JR Hiscock - Molecules, 2020 - mdpi.com
Herein, we present a series of supramolecular self-associating amphiphilic (SSA) salts and
establish the potential for these molecular constructs to act as next-generation solution-state …

Hetero-association of aromatic molecules in aqueous solution

MP Evstigneev - International Reviews in Physical Chemistry, 2014 - Taylor & Francis
Knowledge of the physical chemistry of small molecules complexation (the hetero-
association) in aqueous solution is increasingly important in view of the rapidly emerging …

'Frustrated'hydrogen-bonded self-associated systems as templates towards DNA incorporated nanostructure formation

TL Gumbs, LJ White, NJ Wells… - Supramolecular …, 2018 - Taylor & Francis
Herein, we present the synthesis of a thymine nucleobase-appended 'frustrated'monomer,
which exhibits self-association in DMSO solutions through the formation of hydrogen bonds …

Tuning the Aggregation of N^N^C Pt(II) Complexes by Varying the Aliphatic Side Chain and Auxiliary Halide Ligand: 1H and 195Pt NMR Investigation

MP Evstigneev, AO Lantushenko… - European Journal of …, 2019 - Wiley Online Library
A series of six tridentate cyclometallated N^ N^ C Pt (II) complexes with different halide
auxiliary ligands and different aliphatic side chains have been prepared. All complexes …