This review deals with some key synthetic developments based on the use of iron or cobalt
complexes to promote radical reactivity which have been devised over the last decades. We …

Conspectus Metal-catalyzed cross-couplings have emerged as essential tools for the
construction of C–C bonds. The identification of efficient catalytic systems as well as large …

Chiral 1, 2-diamino compounds are important building blocks in organic chemistry for
biological applications and as asymmetric inducers in stereoselective synthesis that are …

In this study, a simple one-pot construction of β-lactam scaffolds was successfully achieved
via 4, 6-dihydroxysalicylic acid-catalyzed organocatalytic oxidation of amines to imines …

Abstract Evaluation of the relative rates of the cobalt‐catalyzed C (sp2)–C (sp3) Suzuki–
Miyaura cross‐coupling between the neopentylglycol ester of 4‐fluorophenylboronic acid …

Herein, we report a highly efficient and unprecedented approach for heteroarylation of
congested α-bromoamides via electrophilic aromatic substitution of imidazo-heteroarenes …

(Het) aryl migration has emerged as a key synthetic tool and has particularly been exploited
for the synthesis of α-aryl amides. This method overcomes the existing α-arylation methods …

Carbon–carbon bond construction is a long-standing challenge in synthetic organic
chemistry. In the recent years, transition-metal-catalyzed C–C bond forming reactions have …

α-Bromolactones bearing a substituent in the β-position undergo a highly trans-
diastereoselective arylation with arylzinc chlorides in the presence of 10–20% CoCl2 and 10 …

The preparation of the β-lactam motif containing both C–Br and N–O bonds as functional
handles remains an unmet synthetic challenge. Described herein is a novel and highly …