Transition-metal-catalyzed cross-couplings through carbene migratory insertion

Y Xia, D Qiu, J Wang - Chemical reviews, 2017 - ACS Publications
Transition-metal-catalyzed cross-coupling reactions have been well-established as
indispensable tools in modern organic synthesis. One of the major research goals in cross …

Palladium/norbornene cooperative catalysis

J Wang, G Dong - Chemical reviews, 2019 - ACS Publications
Palladium/norbornene cooperative catalysis has emerged as a distinct approach to
construct polyfunctionalized arenes from readily available starting materials. This Review …

Metal–organic cooperative catalysis in C–H and C–C bond activation

DS Kim, WJ Park, CH Jun - Chemical Reviews, 2017 - ACS Publications
Transition-metal-catalyzed activation of C–H and C–C bonds is a challenging area in
synthetic organic chemistry. Among various methods to accomplish these processes, the …

Pd/norbornene: a winning combination for selective aromatic functionalization via C–H bond activation

N Della Ca', M Fontana, E Motti… - Accounts of Chemical …, 2016 - ACS Publications
Conspectus Direct C–H bond activation is an important reaction in synthetic organic
chemistry. This methodology has the potential to simplify reactions by avoiding the use of …

Palladium-catalysed norbornene-mediated C–H functionalization of arenes

J Ye, M Lautens - Nature Chemistry, 2015 - nature.com
The Catellani reaction—a palladium-catalysed C–H functionalization reaction mediated by
norbornene—was first reported in 1997. The capacity to functionalize both the ortho and …

Catalytic methods for aromatic C–H amination: an ideal strategy for nitrogen-based functional molecules

J Jiao, K Murakami, K Itami - ACS Catalysis, 2016 - ACS Publications
Transformations of aromatic compounds into the corresponding amines, amides, and imides
through carbon–hydrogen (C–H) bond functionalization represent one of the most step-and …

Palladium-Catalyzed C–H Amination of C(sp2) and C(sp3)–H Bonds: Mechanism and Scope for N-Based Molecule Synthesis

YN Timsina, BF Gupton, KC Ellis - ACS Catalysis, 2018 - ACS Publications
Nitrogen-containing compounds are the most common structural architectures in drug
candidates, natural and biological products, and small-molecule therapeutics. Within the …

Ortho CH Acylation of Aryl Iodides by Palladium/Norbornene Catalysis

Z Dong, J Wang, Z Ren, G Dong - Angewandte Chemie, 2015 - Wiley Online Library
Ortho CH Acylation of Aryl Iodides by Palladium/Norbornene Catalysis - Dong - 2015 -
Angewandte Chemie - Wiley Online Library Skip to Article Content Skip to Article Information …

Complementary site-selectivity in arene functionalization enabled by overcoming the ortho constraint in palladium/norbornene catalysis

J Wang, R Li, Z Dong, P Liu, G Dong - Nature Chemistry, 2018 - nature.com
Achieving site-selectivity in arene functionalization that is complementary to the site-
selectivity from electrophilic aromatic substitution reactions has been a long-standing quest …

Modular C–H functionalization cascade of aryl iodides

H Shi, DJ Babinski, T Ritter - Journal of the American Chemical …, 2015 - ACS Publications
We report the first example of ipso-borylation for the modular 1, 2-bisfunctionalization of aryl
iodides via C–H functionalization. The carbon–boron bond is used as a lynchpin to access …