Metal–oxo clusters hold great potential in several fields such as catalysis, materials science,
energy storage, medicine, and biotechnology. These nanoclusters of transition metals with …

Polyoxometalates (POMs) have conducive properties such as controlled Brønsted and
Lewis acidity, high thermal stability, nontoxic nature, tunable solubility, and less …

Aqueous solutions of polyoxometalates (POMs) have been shown to have potential as high-
capacity energy storage materials due to their potential for multi-electron redox processes …

Group (IV) metal oxo clusters are a diverse class of compounds with rapidly growing
applications in catalysis, materials chemistry, electronics and optics. They possess unique …

Amide bond construction has garnered significant interest in recent decades due to amides
being one of the most prevalent functional groups among bioactive molecules. Out of the …

Conspectus The selective cleavage of peptide bonds in proteins is of paramount importance
in many areas of the biological and medical sciences, playing a key role in protein …

Photoelectrochemical (PEC) water splitting provides a reasonable and feasible strategy to
capture and transform solar energy, which employs a manner analogous to photosynthesis …

The mono-lacunary Keggin-type polyoxometalate (MLKP)-based crystalline materials are of
significant interest due to their remarkable structural characteristics and functionalities …

Peptide bond formation is a challenging, environmentally and economically demanding
transformation. Catalysis is key to circumvent current bottlenecks. To date, many …

Zr-monosubstituted Lindqvist-type polyoxometalates (Zr-POMs),(Bu4N) 2 [W5O18Zr (H2O)
3](1) and (Bu4N) 6 [{W5O18Zr (μ-OH)} 2](2), have been employed as molecular models to …