“Solvent-in-salt” systems for design of new materials in chemistry, biology and energy research

VA Azov, KS Egorova, MM Seitkalieva… - Chemical society …, 2018 - pubs.rsc.org
Inorganic and organic “solvent-in-salt”(SIS) systems have been known for decades but have
attracted significant attention only recently. Molten salt hydrates/solvates have been …

The role of the hydrogen evolution reaction in the solid–electrolyte interphase formation mechanism for “Water-in-Salt” electrolytes

N Dubouis, P Lemaire, B Mirvaux, E Salager… - Energy & …, 2018 - pubs.rsc.org
Aqueous Li-ion batteries have long been envisioned as safe and green energy storage
technology, but have never been commercially realized owing to the limited electrochemical …

DES-igning the future of drug delivery: A journey from fundamentals to drug delivery applications

S Kapre, SS Palakurthi, A Jain, S Palakurthi - Journal of Molecular Liquids, 2024 - Elsevier
The pharmaceutical industry relies extensively on solvents for various purposes, including
synthesis, crystallization, purification, solubilization, and developing drug delivery systems …

Water dynamics and structure of highly concentrated LiCl solutions investigated using ultrafast infrared spectroscopy

SA Roget, KA Carter-Fenk… - Journal of the American …, 2022 - ACS Publications
In highly concentrated salt solutions, the water hydrogen bond (H-bond) network is
completely disrupted by the presence of ions. Water is forced to restructure as dictated by …

Exploring the chemistry of “Organic/water-in-salt” electrolyte in graphene-polypyrrole based high-voltage (2.4 V) microsupercapacitor

N Kamboj, RS Dey - Electrochimica Acta, 2022 - Elsevier
Aqueous electrolytes are facing substantial barriers for their all-around use in
electrochemical energy storage applications due to their limited operating voltage window …

From networked to isolated: Observing water hydrogen bonds in concentrated electrolytes with two-dimensional infrared spectroscopy

NHC Lewis, B Dereka, Y Zhang… - The Journal of …, 2022 - ACS Publications
Superconcentrated electrolytes have emerged as a promising class of materials for energy
storage devices, with evidence that high voltage performance is possible even with water as …

Dynamics of water molecules and ions in concentrated lithium chloride solutions probed with ultrafast 2D IR spectroscopy

R Yuan, MD Fayer - The Journal of Physical Chemistry B, 2019 - ACS Publications
Water and ion dynamics in concentrated LiCl solutions were studied using ultrafast 2D IR
spectroscopy with the methyl thiocyanate (MeSCN) CN stretch as the vibrational probe. The …

Ion/water network structural dynamics in highly concentrated lithium chloride and lithium bromide solutions probed with ultrafast infrared spectroscopy

SA Roget, TR Heck, KA Carter-Fenk… - The Journal of Physical …, 2023 - ACS Publications
The structural dynamics of highly concentrated LiCl and LiBr aqueous solutions were
observed from 1–4 to 1–16 water molecules per ion pair using ultrafast polarization …

Water-in-bisalt electrolyte with record salt concentration and widened electrochemical stability window

J Forero-Saboya, E Hosseini-Bab-Anari… - The journal of …, 2019 - ACS Publications
Water-in-salt and water-in-bisalt electrolytes have recently attracted much attention due to
their expanded electrochemical stability windows. The concentration limit of such …

Dynamics and spectral response of water molecules around tetramethylammonium cation

A Biswas, A Priyadarsini, BS Mallik - The Journal of Physical …, 2019 - ACS Publications
Till now, there has been ambiguity about the structural heterogeneity inside a solute
solvation shell and the dynamical response of the surrounding solvent molecules. To …