“Solvent-in-salt” systems for design of new materials in chemistry, biology and energy research
Inorganic and organic “solvent-in-salt”(SIS) systems have been known for decades but have
attracted significant attention only recently. Molten salt hydrates/solvates have been …
attracted significant attention only recently. Molten salt hydrates/solvates have been …
The role of the hydrogen evolution reaction in the solid–electrolyte interphase formation mechanism for “Water-in-Salt” electrolytes
Aqueous Li-ion batteries have long been envisioned as safe and green energy storage
technology, but have never been commercially realized owing to the limited electrochemical …
technology, but have never been commercially realized owing to the limited electrochemical …
DES-igning the future of drug delivery: A journey from fundamentals to drug delivery applications
The pharmaceutical industry relies extensively on solvents for various purposes, including
synthesis, crystallization, purification, solubilization, and developing drug delivery systems …
synthesis, crystallization, purification, solubilization, and developing drug delivery systems …
Water dynamics and structure of highly concentrated LiCl solutions investigated using ultrafast infrared spectroscopy
SA Roget, KA Carter-Fenk… - Journal of the American …, 2022 - ACS Publications
In highly concentrated salt solutions, the water hydrogen bond (H-bond) network is
completely disrupted by the presence of ions. Water is forced to restructure as dictated by …
completely disrupted by the presence of ions. Water is forced to restructure as dictated by …
Exploring the chemistry of “Organic/water-in-salt” electrolyte in graphene-polypyrrole based high-voltage (2.4 V) microsupercapacitor
Aqueous electrolytes are facing substantial barriers for their all-around use in
electrochemical energy storage applications due to their limited operating voltage window …
electrochemical energy storage applications due to their limited operating voltage window …
From networked to isolated: Observing water hydrogen bonds in concentrated electrolytes with two-dimensional infrared spectroscopy
Superconcentrated electrolytes have emerged as a promising class of materials for energy
storage devices, with evidence that high voltage performance is possible even with water as …
storage devices, with evidence that high voltage performance is possible even with water as …
Dynamics of water molecules and ions in concentrated lithium chloride solutions probed with ultrafast 2D IR spectroscopy
Water and ion dynamics in concentrated LiCl solutions were studied using ultrafast 2D IR
spectroscopy with the methyl thiocyanate (MeSCN) CN stretch as the vibrational probe. The …
spectroscopy with the methyl thiocyanate (MeSCN) CN stretch as the vibrational probe. The …
Ion/water network structural dynamics in highly concentrated lithium chloride and lithium bromide solutions probed with ultrafast infrared spectroscopy
SA Roget, TR Heck, KA Carter-Fenk… - The Journal of Physical …, 2023 - ACS Publications
The structural dynamics of highly concentrated LiCl and LiBr aqueous solutions were
observed from 1–4 to 1–16 water molecules per ion pair using ultrafast polarization …
observed from 1–4 to 1–16 water molecules per ion pair using ultrafast polarization …
Water-in-bisalt electrolyte with record salt concentration and widened electrochemical stability window
J Forero-Saboya, E Hosseini-Bab-Anari… - The journal of …, 2019 - ACS Publications
Water-in-salt and water-in-bisalt electrolytes have recently attracted much attention due to
their expanded electrochemical stability windows. The concentration limit of such …
their expanded electrochemical stability windows. The concentration limit of such …
Dynamics and spectral response of water molecules around tetramethylammonium cation
Till now, there has been ambiguity about the structural heterogeneity inside a solute
solvation shell and the dynamical response of the surrounding solvent molecules. To …
solvation shell and the dynamical response of the surrounding solvent molecules. To …