Photoactive Metal-to-Ligand Charge Transfer Excited States in 3d6 Complexes with Cr0, MnI, FeII, and CoIII
Many coordination complexes and organometallic compounds with the 4d6 and 5d6
valence electron configurations have outstanding photophysical and photochemical …
valence electron configurations have outstanding photophysical and photochemical …
Luminescent first-row transition metal complexes
C Wegeberg, OS Wenger - Jacs Au, 2021 - ACS Publications
Precious and rare elements have traditionally dominated inorganic photophysics and
photochemistry, but now we are witnessing a paradigm shift toward cheaper and more …
photochemistry, but now we are witnessing a paradigm shift toward cheaper and more …
Accessing photoredox transformations with an iron (III) photosensitizer and green light
A Aydogan, RE Bangle, A Cadranel… - Journal of the …, 2021 - ACS Publications
Efficient excited-state electron transfer between an iron (III) photosensitizer and organic
electron donors was realized with green light irradiation. This advance was enabled by the …
electron donors was realized with green light irradiation. This advance was enabled by the …
The great strides of iron photosensitizers for contemporary organic photoredox catalysis: On our way to the holy grail?
The scarcity of 2 nd and 3 rd row transition metals such as ruthenium, iridium, rhodium and
osmium, coupled with a global desire for sustainable chemistry has led to the resurgence of …
osmium, coupled with a global desire for sustainable chemistry has led to the resurgence of …
Molecular Design Principles to Elongate the Metal-to-Ligand Charge Transfer Excited-State Lifetimes of Square-Planar Nickel (II) Complexes
Square-planar NiII complexes and their electronically excited states play key roles in cross-
coupling catalysis and could offer new opportunities to complement well-known …
coupling catalysis and could offer new opportunities to complement well-known …
Using X-ray free-electron lasers for spectroscopy of molecular catalysts and metalloenzymes
The metal centres in metalloenzymes and molecular catalysts are responsible for the
rearrangement of atoms and electrons during complex chemical reactions, and they enable …
rearrangement of atoms and electrons during complex chemical reactions, and they enable …
Photoactive iron complexes: more sustainable, but still a challenge
On transition metals such as iron rests lots of hope to replace precious metal catalysts in the
field of photochemistry for a more sustainable future. Indeed, significant progress has been …
field of photochemistry for a more sustainable future. Indeed, significant progress has been …
First‐Row d6 Metal Complex Enables Photon Upconversion and Initiates Blue Light‐Dependent Polymerization with Red Light
Photosensitizers for sensitized triplet‐triplet annihilation upconversion (sTTA‐UC) often rely
on precious heavy metals, whereas coordination complexes based on abundant first‐row …
on precious heavy metals, whereas coordination complexes based on abundant first‐row …
KiMoPack: A python Package for Kinetic Modeling of the Chemical Mechanism
C Müller, T Pascher, A Eriksson… - The Journal of …, 2022 - ACS Publications
Herein, we present KiMoPack, an analysis tool for the ki netic mo deling of transient
spectroscopic data. KiMoPack enables a state-of-the-art analysis routine including data …
spectroscopic data. KiMoPack enables a state-of-the-art analysis routine including data …
Progress in the theory of x-ray spectroscopy: From quantum chemistry to machine learning and ultrafast dynamics
CD Rankine, TJ Penfold - The Journal of Physical Chemistry A, 2021 - ACS Publications
The development of high-brilliance third-and fourth-generation light sources such as
synchrotrons and X-ray free-electron lasers (XFELs), the emergence of laboratory-based X …
synchrotrons and X-ray free-electron lasers (XFELs), the emergence of laboratory-based X …