While hydrogen plays an ever-increasing role in modern society, nature has utilized
hydrogen since a very long time as an energy carrier and storage molecule. Among the …

Hydrogenase enzymes efficiently process H2 and protons at organometallic FeFe, NiFe, or
Fe active sites. Synthetic modeling of the many H2ase states has provided insight into …

This article sets out to review the chemistry relating to the synthesis of structural and
functional analogues of the three classes of hydrogenases. This chemistry has grown …

This tutorial review is aimed at chemical scientists interested in understanding and
exploiting the remarkable catalytic behavior of the hydrogenases. The key structural features …

C–H bond formation with CO2 to selectively form products such as formate (HCOO–) is an
important step in harnessing CO2 emissions as a carbon-neutral or carbon-negative …

Extended investigation of electrocatalytic generation of dihydrogen using [(μ-1, 2-
benzenedithiolato)][Fe (CO) 3] 2 has revealed that weak acids, such as acetic acid, can be …

Recent developments have helped to extend the repertoire of mixed‐valent ruthenium and
osmium complexes beyond conventional systems. This extension has been achieved by …

Electrochemical reduction of Fe2 (μ-pdt)(CO) 6 1 (pdt= propane-1, 3-dithiolate) leads initially
to a short-lived species, 1-, then subsequently to two-electron reduced products, including a …

This review focuses on electron and proton transfers involving hexacarbonyl and substituted
{2Fe2S} complexes inspired from the active site of the [FeFe]-hydrogenases ([FeFe] …

The design of electrocatalysts that will selectively transfer hydride equivalents to either H+ or
CO2 to afford H2 or formate is a long-standing goal in molecular electrocatalysis. In this …