Spin-crossover in the Fe (4X-pyridine) 2 [Fe (CN) 5 NO] series with X= Cl, Br, and I. Role of the distortion for the iron atom coordination environment
This contribution reports the thermally induced spin crossover (SCO) in the titled series of
hybrid solids from the magnetic (SQUID), DSC, IR, Raman, and Mössbauer data. The onset …
hybrid solids from the magnetic (SQUID), DSC, IR, Raman, and Mössbauer data. The onset …
Pressure-Induced Hysteretic and Abrupt Spin Transition in Amine Functionalized Isoquinoline-Based Two-Dimensional FeII Hofmann Frameworks
Two two-dimensional (2D) Hofmann-type coordination frameworks are synthesized by
employing the square planar tetracyanometallate building blocks and an amine …
employing the square planar tetracyanometallate building blocks and an amine …
Spin crossover in Hofmann-like coordination polymers. Effect of the axial ligand substituent and its position
This contribution reports the preparation and thermally induced spin crossover (SCO) in the
Hofmann-like Fe (3-hydroxypyridine) 2 [M (CN) 4] series, where M= Ni, Pd, and Pt. These …
Hofmann-like Fe (3-hydroxypyridine) 2 [M (CN) 4] series, where M= Ni, Pd, and Pt. These …
Thermally-induced spin-crossover (SCO) in Fe (4-ethynylpyrdine) 2 [Fe (CN) 5 NO]. Why is the SCO observed in 2D ferrous nitroprussides despite the NO–NC …
Pillared ferrous nitroprussides form an interesting series of coordination polymers where the
spin crossover (SCO) behavior has been observed for several pillar organic molecules. This …
spin crossover (SCO) behavior has been observed for several pillar organic molecules. This …
Fe(L)2[M(CN)4] with L = 4-Ethyl Isonicotinate and M = Ni, Pd, Pt.─A Series of Hofmann-Type Frameworks with Spin Crossover: The Dominant Role of the Fe–NC …
This contribution reports the incorporation of an organic pillar (L), 4-ethyl isonicotinate,
between adjacent layers of the series of 2D coordination polymers, Fe [M (CN) 4], with M …
between adjacent layers of the series of 2D coordination polymers, Fe [M (CN) 4], with M …
Spin-crossover in [Fe (Quinazoline) 2][Fe (CN) 5NO]. Evidence of its framework flexibility
The titled material shows a thermally induced spin-crossover (SCO) in the 75–150 K
temperature region, with a narrow hysteresis of about 3 K. The recorded DSC data show a …
temperature region, with a narrow hysteresis of about 3 K. The recorded DSC data show a …
Optical characterization of isothermal spin state switching in an Fe (II) spin crossover molecular and polymer ferroelectric bilayer
S Yazdani, K Collier, G Yang, J Phillips… - Journal of Physics …, 2023 - iopscience.iop.org
Using optical characterization, it is evident that the spin state of the spin crossover molecular
complex [Fe {H 2 B (pz) 2} 2 (bipy)](pz= tris (pyrazol-1-1y)-borohydride, bipy= 2, 2ʹ …
complex [Fe {H 2 B (pz) 2} 2 (bipy)](pz= tris (pyrazol-1-1y)-borohydride, bipy= 2, 2ʹ …
Chemical CO 2 fixation using a cyanido bridged heterometallic Zn (ii)–Mn (ii) 2D coordination polymer
P Dadmehr, R Bikas, T Lis - Dalton Transactions, 2024 - pubs.rsc.org
A new cyanido bridged Zn (II)–Mn (II) mixed-metal coordination polymer,{[Zn (μ-L)(μ-CN)
2Mn0. 5]·(CH3OH)} n (1), has been synthesized by the reaction of Zn (CN) 2, Mn (II) salts …
2Mn0. 5]·(CH3OH)} n (1), has been synthesized by the reaction of Zn (CN) 2, Mn (II) salts …
Crystal structures and properties of Fe(H2O)2[Ni(CN)4]·nH2O hydrates
L Torres, AA Lemus-Santana, L Sánchez… - Journal of …, 2023 - Taylor & Francis
We report the crystal structures and properties of iron hydrate compounds. These hydrates
have 2D topologies and crystallize with three different structural features depending on the …
have 2D topologies and crystallize with three different structural features depending on the …
The nature of the atypical kinetic effects observed for the thermally induced spin transition in ferrous nitroprussides with short organic pillars
In pillared 2D ferrous nitroprussides, Fe (L) x [Fe (CN) 5NO] where x= 1, 2, and L is an
appropriate organic molecule, the axial CN and NO groups are dangling ligands found in …
appropriate organic molecule, the axial CN and NO groups are dangling ligands found in …